FIELD: physics; fuel.
SUBSTANCE: method is suggested for preparation of hard oxide fuel element (HOFE), which includes the following stages: preparation of substrate layer for anode, application of anode layer onto substrate layer, application of electrolyte layer onto anode layer, baking of prepared structure. At that layer of substrate and/or anode layer contain composition including alloyed zirconium oxide, alloyed oxide of cerium and/or oxide of metal having oxygen-ion or proton conductivity, nickel oxide and at least one oxide selected from the group that contains the following components Al2O3, TiO2, Cr2O3, Sc2O3, VOx, TaOx, MnOx, NbOx, CaO, Bi2O3, LnOx, MgCr2O4, MgTiO3, CaAl2O4, LaAlO3, YbCrO3, ErCrO4, NiTiO3, NiCrO4 and their mixtures. Mentioned composition makes it possible to prevent enlargement of nickel particles by means of introduction of special inhibitors of their growth and, at the same time, to increase strength of ceramic structure of substrate layer and/or anode layer.
EFFECT: increased resistance of anode of hard-oxide fuel element.
15 cl, 11 ex
Title | Year | Author | Number |
---|---|---|---|
REVERSIBLE SOLID OXIDE FUEL ELEMENT (ITS VERSIONS) | 2008 |
|
RU2480865C2 |
SOLID OXIDE FUEL CELL | 2008 |
|
RU2399996C1 |
CERAMIC-METAL ANODE STRUCTURE (ITS VERSIONS) AND ITS APPLICATION | 2008 |
|
RU2480863C2 |
METHOD OF MAKING SOLID OXIDE FUEL CELL ON METAL BASE | 2014 |
|
RU2571824C1 |
SOLID OXIDE FUEL CELL | 2005 |
|
RU2356132C2 |
PACK OF CONVERTIBLE SOLID-OXIDE FUEL ELEMENTS AND METHOD OF ITS FABRICATION | 2006 |
|
RU2373616C1 |
METHOD OF SHRINKAGE AND POROSITY CONTROL AT SINTERING OF MULTY-LAYER STRUCTURES | 2006 |
|
RU2370343C2 |
SOLID OXIDE FUEL CELLS WITH BEARING ANODE AND CERMET IONOGEN | 2004 |
|
RU2342740C2 |
REMOVAL OF IMPURITY PHASES FROM ELECTROCHEMICAL DEVICES | 2008 |
|
RU2446515C2 |
CERAMIC ANODE STRUCTURE (ITS VERSIONS) AND ITS APPLICATION | 2008 |
|
RU2479893C2 |
Authors
Dates
2009-04-27—Published
2006-01-31—Filed