FIELD: packing and storage.
SUBSTANCE: invention relates to a method of producing a lid or cap. Method involves obtaining a polypropylene composition through sequential polymerisation, which involves the following steps: A) polymerisation in a first reactor, which is a loop reactor, in the presence of a Ziegler-Natta catalyst, propylene-containing monomers, and, optionally, one or more comonomers selected from ethylene and C4-C10 alpha-olefins, to obtain a first fraction of propylene polymer having a comonomer content of 0.0 to 1.8 wt.% and MFR 2 from 12.0 to 40.0 g/10 min, measured in accordance with ISO 1133 at 230 °C load 2.16 kg; B1) polymerisation in a second reactor, which is a first gas-phase reactor, of monomers containing propylene, and one or more comonomers selected from ethylene and C4-C10 alpha-olefins, in the presence of said first propylene polymer fraction, to obtain a second propylene polymer fraction, C) melting, extruding and moulding the polypropylene composition in the presence of at least one nucleating agent to form a lid or cap; and D) cooling the lid or cap obtained in step (C) at rate of 50 K/s or more. Polypropylene composition containing said first and second fractions of propylene polymer has MFR2 from 12.0 to 60.0 g/10 min, measured in accordance with ISO 1133 at 230 °C under load of 2.16 kg, has comonomer content from 2.2 to 5.0 wt.%, and ratio of comonomer content in component A) to comonomer content in said polypropylene composition is 0.35 or less.
EFFECT: providing a method of producing a lid or a cap with a shorter cycle for making the lid or cap due to faster crystallisation of the polypropylene composition in a wide range of cooling rates and especially at high cooling rates.
11 cl, 2 dwg, 4 tbl, 2 ex
Title | Year | Author | Number |
---|---|---|---|
NUCLEIED POLYPROPYLENE COMPOSITION FOR CONTAINERS | 2013 |
|
RU2623430C2 |
POLYPROPYLENE COMPOSITION WITH IMPROVED SHOCK STRENGTH FOR APPLICATION IN PIPES | 2014 |
|
RU2626395C2 |
HETEROPHASE POLYPROPYLENE WITH IMPROVED HARDNESS TO TRANSPARENCY RATIO | 2010 |
|
RU2499804C1 |
POLYPROPYLENE-BASED FILM | 2021 |
|
RU2815096C1 |
POLYPROPYLENE COMPOSITION WITH IMPROVED MANUFACTURABILITY AND IMPACT | 2020 |
|
RU2798417C1 |
COMPOSITION OF MULTIMODAL POLYPROPYLENE FOR APPLICATION IN PIPES | 2014 |
|
RU2625794C2 |
POLYOLEFIN COMPOSITION WITH IMPROVED IMPACT STRENGTH AND BLUSHING RESISTANCE | 2019 |
|
RU2782633C1 |
MULTIMODAL POLYPROPYLENE COMPOSITION FOR APPLICATION IN PIPES | 2014 |
|
RU2626394C2 |
POLYPROPYLENE-BASED COMPOSITION HAVING LOW WELDING START TEMPERATURE AND HIGH MELTING POINT | 2017 |
|
RU2724050C1 |
COMPOSITION | 2019 |
|
RU2813714C2 |
Authors
Dates
2024-09-03—Published
2020-04-28—Filed