FIELD: organic chemistry. SUBSTANCE: product: O-[2-(4-phenoxyphenoxy)ethyl] -N, N′-dimethyldiamidothiophosph- ate, empirical formula is C16H21N2O3PS, yield is 77% , m. p. is 52.5-53 C; O-[2-(4-phenoxyphenoxy)ethyl] -N, N′-diethyldiamidothiophospha- te, empirical formula is C18H25N2O3PS, yield is 51%, m. p. is 59-60 C; O-[2-(4-phenoxyphenoxy)ethyl] -N, N′-dipropyldiamidothiophosph- ate, empirical formula is C20H29N2O3PS, yield is 56$, nD20 = 1.5610. Reagent 1: dichloroanhydride of O-[2-(4-phenoxyphenoxy)ethylthiophosphoric acid. Reagent 2: alkylamine. Reaction conditions: in the medium of organic solvent. Synthesized compounds are used in agriculture. EFFECT: improved method of synthesis. 2 tbl
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Authors
Dates
1994-12-30—Published
1990-08-17—Filed