FIELD: chemical technology. SUBSTANCE: process is carried out by contacting monomer of ethylene and/or propylene with catalyst in organic solvent medium at 0-100 C under pressure 0.1-4 MPa. Catalyst used: tri-C1-C6-alkylaluminium, tetra-C1-C6-alkoxytitanium and organic compound where - C1-C4-alkyl; X - Cl, Br, J; n = 1 or 2; m = 0 or 1 at the molar ratio (100-1):1:(0.2-5). Under these conditions process selectivity is increased by butene-1 from 78.3% to 97.8% and output up to 5200 g/g Tl x r. EFFECT: increased selectivity and output. 3 cl, 1 tbl
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Authors
Dates
1996-04-27—Published
1987-03-11—Filed