FIELD: polymer production.
SUBSTANCE: cracking-resistant tetrafluoroethylene/ethylene copolymer is obtained through copolymerization of above monomers in an aqueous medium in presence of free radical-type initiator. Reaction medium, prior to be charged with monomers, is supplemented with alkali or ammonium salts of monobasic perfluoro- or ω-monohydrogenperfluorocarboxylic acids with 7-11 carbon atoms in amount 0.2 to 0.8% based on the weight of monomers.
EFFECT: reduced cost of product and simplified technology thereof.
1 tbl, 9 ex
Title | Year | Author | Number |
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METHOD OF PRODUCING HEAT-RESISTANT AND CRACK-RESISTANT COPOLYMERS OF TETRAFLUOROETHYLENE WITH ETHYLENE | 2008 |
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RU2395530C2 |
MODIFIED TETRAFLUOROETHYLENE/ETHYLENE COPOLYMER PRODUCTION PROCESS | 1999 |
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RU2649143C1 |
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RU2398789C1 |
METHOD OF (CO)POLYMERIZATION OF FLUORINATED OLEFIN MONOMERS | 1994 |
|
RU2128667C1 |
METHOD OF PREPARING AQUEOUS DISPERSION OF TETRAFLUOROETHYLENE COPOLYMER | 1999 |
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RU2158275C1 |
PROCESS FOR PRODUCTION OF THERMOPLASTIC HYDROGEN- CONTAINING FLUOROPOLYMERS | 1995 |
|
RU2136700C1 |
PROCESS FOR PREPARING COPOLYMERS | 1994 |
|
RU2071479C1 |
PROCESS FOR PRODUCTION TETRAFLUOROETHYLENE COPOLYMERS WITH 2-5 MOL % OF PERFLUOROPROPYL VINYL ETHER | 1999 |
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RU2156777C1 |
METHOD OF TETRAFLUOROETHYLENE COPOLYMERS PRODUCING (VARIANTS) | 1994 |
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RU2100378C1 |
Authors
Dates
2006-06-27—Published
1978-03-02—Filed