FIELD: chemistry.
SUBSTANCE: invention relates to field of obtaining low-molecular rubbers and can be applied in oil-chemical industry. Low molecular rubbers are obtained by polymerisation of coupled dienes or by their copolymerisation between each other and/or with vinyl monomers in mass or in medium of hydrocarbon solvent at 60-120°C and 7-10 kgf/cm2 in presence of radical initiators and regulators with following distillation of non- polymerised monomers or their mixtures with hydrocarbons from polymerisate with water steam, being subjected to degassing at temperature of polymerisation for pressure 0.1-4.0 kgf/cm2 before processing with water steam. At degassing it is possible to have content of initiator in polymerisate 0.1-1.5 wt %.
EFFECT: process intensification.
2 cl, 3 tbl, 3 ex
Title | Year | Author | Number |
---|---|---|---|
LIQUID LOW-MOLECULAR WEIGHT RUBBER MANUFACTURING PROCESS | 1976 |
|
SU1840600A1 |
METHOD OF OBTAINING LOW-MOLECULAR CARBO-CHAIN POLYMERS | 1979 |
|
SU1840785A1 |
LOW-MOLECULAR WEIGHT RUBBER MANUFACTURING PROCESS | 1977 |
|
SU1840584A1 |
METHOD OF SEPARATING LOW-MOLECULAR DIENE RUBBERS FROM POLYMERISATE | 1976 |
|
SU1840786A1 |
METHOD OF OBTAINING BUTADIENE-NITRILE RUBBER | 0 |
|
SU792904A1 |
FILLED BUTADIENE-STYRENE RUBBER MANUFACTURING PROCESS | 2005 |
|
RU2291157C1 |
FILLED BUTADIENE-STYRENE RUBBER MANUFACTURING PROCESS | 2005 |
|
RU2291159C1 |
FILLED BUTADIENE-STYRENE RUBBER MANUFACTURING PROCESS | 2005 |
|
RU2291158C1 |
PROCESS FOR PURIFYING SYNTHETIC BUTADIENE LATEXES | 0 |
|
SU939449A1 |
Authors
Dates
2009-08-20—Published
1977-03-21—Filed