FIELD: catalysts for polymerization. SUBSTANCE: catalyst has cyclopentadienyl-compound of the general formula 1 (R1), where M - zirconium or germanium; Y - silicon or germanium; R1-methyl or tert. -butyl. Position R2 in cyclopentadienyl-ring and its type correspond configuration, in which any symmetry plane is absent involving M; R3 - methyl or cyclotetramethylene; n and q - are whole numbers 0-4. When n= q= O or n= q= 4, alumineoxane of the general formula 11 () or 111 () is excluded, where - methyl, m= 13.3, and at molar ratio aluminium: transient metal = 5000-20000. EFFECT: enhanced quality of catalyst.
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Authors
Dates
1994-02-15—Published
1988-11-09—Filed