FIELD: organic chemistry. SUBSTANCE: product: (2-N,N-diethylaminoethyl)-4′-hydroxy-3′,5′-di-tert. -butylbenzy- lsulfide which can be used as a stabilizing agent for carbon-chain polymers. Synthesis is carried out reaction of Mannich base with 2-diethylaminoethanethiol at 120-130 C with aminothiol excess distillation off at 2 mm mercury column. Yield is 98%, mol. mass is 346. Use of new substance at concentration 1 wt.-% in rubber SKS-30 ARKP provides increase of plasticity retention index under conditions of heat ageing at 140 C for 30 min from 94 to 96.9%. EFFECT: synthesis of compound of class indicated above showing enhanced effectiveness. 2 dwg, 6 tbl
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(2-N,N-DIETHYLAMINOETHYL)-4′-HYDROXY-3′,5′-DI-TERT-BUTYLBENZYL- SULFIDE AS A COAGULATING AGENT OF EMULSION RUBBERS | 1989 |
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Authors
Dates
1995-01-20—Published
1989-12-04—Filed