FIELD: organic chemistry. SUBSTANCE: product: N,N'-diphenyloxide of dicarboxylic acid of the formula (I) where Z - simple bond or O; m. p. is 296-298 C and 266-267 C; yield is 92 and 94%. Reagent 1: N,N'-bis- (2,4-dinitrophenyl) -amide of 4,4'- diphenyl- or -4,4'- diphenyloxide of dicarboxylic acid. Reaction conditions: liquid-phase reduction with hydrogen under increased pressure and temperature on the palladium catalyst in the medium of amide solvent. Synthesized products were used as intermediate substances for synthesis of 4,4'-bis- [5(6)-aminobenzimidazolyl -2]-diphenyl or -diphenyloxide. EFFECT: improved method of synthesis. 1 tbl
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Authors
Dates
1995-01-27—Published
1992-01-03—Filed