FIELD: organic chemistry. SUBSTANCE: azabicycloalkane having formula 1 where R2-R7 represent independently hydrogen or C1-C4 alkyl, C6H5 or NO2 is used as reagent 1. Y is COOR-group, CON(R1)2 or CN where R and R1 represent independently hydrogen or C1-C4 alkyl. Compound of trivalent phosphorous having formula 2 is used as reagent 2 or 3. Reaction is carried out at 25-200 C in the presence of acid or solvent. Structure of compounds having formula 1, 2 and 3 are given in specification PX3 (II), . EFFECT: improves efficiency of the method.
Authors
Dates
1995-04-10—Published
1989-11-13—Filed