5,6-DISUBSTITUTED 3-PYRIDYLMETHYLAMMONIUM HALOGENIDES, METHOD OF THEIR SYNTHESIS AND METHODS OF SYNTHESIS 5-(SUBSTITUTED METHYL)-2,3-PYRIDINE CARBOXYLIC ACIDS Russian patent published in 1997 - IPC

Abstract RU 2090558 C1

FIELD: organic chemistry, chemical technology. SUBSTANCE: products: 5,6-disubstituted 3-pyridylmethylammonium halogenides of the formula (I) given in description where: Z and Z1 - H; X - Cl, Br or J; Y and y1 - OR4; R4 - H, C1-C4-alkyl; Q - RR1R2-N-, or nitrogen-containing heterocycle, R, R1 and R2 - C1-C4-alkyl. Reagent 1: compound of the formula (II) given in description where: Z, Z1, Y and y1 as indicated above. Method involves interaction with halogenating agent in medium of inert organic solvent in the presence of radical initiating agent followed by treatment of the formed reaction mixture with 1 mole trialkylamine. Synthesized compounds were used as semiproducts for synthesis of herbicides. EFFECT: improved method of synthesis. 1 tbl, 10 cl

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RU 2 090 558 C1

Authors

Genri Li Strong[Us]

Dates

1997-09-20Published

1993-05-11Filed