FIELD: organic chemistry, chemical technology. SUBSTANCE: products: 5,6-disubstituted 3-pyridylmethylammonium halogenides of the formula (I) given in description where: Z and Z1 - H; X - Cl, Br or J; Y and y1 - OR4; R4 - H, C1-C4-alkyl; Q - RR1R2-N⊕-, or nitrogen-containing heterocycle, R, R1 and R2 - C1-C4-alkyl. Reagent 1: compound of the formula (II) given in description where: Z, Z1, Y and y1 as indicated above. Method involves interaction with halogenating agent in medium of inert organic solvent in the presence of radical initiating agent followed by treatment of the formed reaction mixture with 1 mole trialkylamine. Synthesized compounds were used as semiproducts for synthesis of herbicides. EFFECT: improved method of synthesis. 1 tbl, 10 cl
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