FIELD: organic chemistry. SUBSTANCE: the product: tetrafluorophthalic acid of the empirical formula: C8H2O4F4, mp 152-153 C. Reagent 1: octafluoronaphthyl. Reagent 2: 29-34% aqueous hydrogen peroxide. Reaction conditions: 60-80 C; a water-miscible organic solvent, silica gel having 100- 2000 mcm fractions with a pH o 6.0-7.0 at an octafluoronaphthalene to hydrogen peroxide to silica gel ratio of 1.5-5:25-75:5-20. EFFECT: greater efficiency of the process.
Authors
Dates
1995-06-19—Published
1992-04-30—Filed