CYCLOPROPANECARBOXYLIC ACID PYRAZOLIDES IN THE FORM MIXTURE OF DIASTEREOMERS AS INTERMEDIATE COMPOUNDS FOR PREPARATION PYPETROIDS Russian patent published in 1997 - IPC

Abstract RU 2095351 C1

FIELD: organic chemistry. SUBSTANCE: present invention describes cyclopropanecarboxylic acid pyrazolides of formula I: wherein R1 is Cl, CF3. Said compounds are used as intermediate compounds for preparation of optically active pyrethroid compounds. Compound I is prepared with yield of 93 % from pyrazole II: and racemic cyclopropane carboxylic acid III: by treatment with thionyl chloride in the presence of triethylamine in ether. Compounds I are advantageous in that they are technologically more simple to obtain and can be more readily converted into optionally active pyrethroids. EFFECT: improved properties of the title compounds.

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RU 2 095 351 C1

Authors

Popov S.A.

Tkachev A.V.

Dates

1997-11-10Published

1995-07-06Filed