CHROMATOGRAPHIC METHOD FOR DETERMINING CORRECTION SENSITIVITY COEFFICIENTS TO SUBSTANCES HAVING SIMILAR PROPERTIES Russian patent published in 1995 - IPC

Abstract RU 2046336 C1

FIELD: measurement technology. SUBSTANCE: method involves analyzing two mixtures prepared from the initial mixture by adding different quantities of two or more standard substances from the same homologic series or additives. Each mixture is analyzed chromatographically twice using different arbitrary quantities of samples to be introduced. The difference of chromatographic signals is used to determine the values of analyzed components by means of internal double standard interpolation method. The determined differences of areas under peaks corresponding to the standard substances are used to calculate their reduced values by extrapolating the relation rст=⊘(ΔQст) to the mean contents of analyzed components. The reduced differences of areas under peaks corresponding to these components is obtained by interpolating the calculated reduced differences of areas of peaks corresponding to two neighboring homologs of standard substances. The ratio of reduced differences of areas under peaks corresponding to one of the standard substances and analyzed components is used to determine the correction sensitivity coefficient for these components. EFFECT: enhanced accuracy of the method. 1 tbl

Similar patents RU2046336C1

Title Year Author Number
PROCESS OF CHROMATOGRAPHIC DETERMINATION OF CONCENTRATIONS OF COMPONENTS OF COMPLEX MIXTURE 1992
  • Arutjunov Ju.I.
  • Vigdergauz M.S.
RU2044316C1
CHROMATOGRAPHIC METHOD OF DETERMINATION OF CONCENTRATIONS OF COMPONENTS 1992
  • Arutjunov Ju.I.
  • Vigdergauz M.S.
RU2044317C1
CHROMATOGRAPHIC METHOD FOR DETERMINING INGREDIENTS CONCENTRATION IN COMPLEX MIXTURE 1992
  • Vigdergauz M.S.
  • Arutjunov Ju.I.
RU2046335C1
METHOD DETERMINING MOLAR COEFFICIENTS OF SENSITIVITY OF DETECTORS BY THERMAL CONDUCTIVITY AND IONIZATION OF FLAME 1997
  • Arutjunov Ju.I.
  • Kurbatova S.V.
  • Platonov I.A.
  • Kudrjashov S.Ju.
  • Medvedeva M.Eh.
RU2137123C1
CHROMATOGRAPHIC METHOD DETERMINING MOLECULAR MASS 1998
  • Arutjunov Ju.I.
  • Onuchak L.A.
  • Kudrjashov S.Ju.
  • Guzenko O.G.
RU2145709C1
CHROMATOGRAPHIC DEVICE FOR DETERMINATION OF EXTRAPOLATED VALUES OF RETENTION 1992
  • Vigdergauz M.S.
  • Arutjunov Ju.I.
RU2044318C1
METHOD OF CHROMATOGRAPHIC IDENTIFICATION OF COMPONENTS OF COMPLEX MIXTURES OF ORGANIC COMPOUNDS 1994
  • Vigdergauz M.S.
  • Aruponov Ju.I.
  • Lobachev A.L.
  • Revinskaja E.V.
  • Platonov I.A.
RU2069363C1
METHOD AND DEVICE FOR SUPPLYING SAMPLE FOR GAS-CHROMATOGRAPHIC ANALYSIS OF HYDROCARBONS IN OILS 2003
  • Arutjunov Ju.I.
  • Platonov I.A.
  • Zanozina I.I.
  • Zanozin I.Ju.
  • Diskina D.E.
RU2250460C2
METHOD OF CHROMATOGRAPHIC IDENTIFICATION OF COMPONENTS OF COMPLEX MIXTURES 0
  • Vigdergauz Mark Solomonovich
  • Kurbatova Svetlana Viktorovna
  • Lange Petr Konstantinovich
  • Kolosova Elena Aleksandrovna
SU1804625A3
METERING COCK FOR CHROMATOGRAPHER 1992
  • Arutjunov Ju.I.
  • Platonov I.A.
  • Lobachev A.L.
RU2069365C1

RU 2 046 336 C1

Authors

Vigdergauz M.S.

Arutjunov Ju.I.

Dates

1995-10-20Published

1992-09-01Filed