FIELD: organic chemistry. SUBSTANCE: product: compound of the formula (I) where R′ is lower alkyl which can be substituted with halogen; R″ H, lower alkyl nonobligatory substituted with halogen, lower alkoxy, methylthio, methoxyethyleneoxy or phenyl, lower alkynyl group or X′-group where COX′ lower alkyl; Z CH=CH-group or CH2-N = C(R4)-group; the right dash is a bond directed to R3:R3-phenyl which is nonobligatory substituted with a single substituent. The latter is taken from halogen, lower alkyl, trifluoromethyl, cyano, lower alkoxy, lower haloidoxy, lower alkenyloxy, trifluoromethanesulfonyloxy, lower alkylthio, lower alkylsulfonyl, lower alkylsulfinyl, dimethylcarbamoyloxy, phenyl and pyrrolyl; two substituents taken from halogen, lower alkyl, trofluoromethyl, lower alkoxy and lower alkenyloxy or three substituents taken from the lower alkyl and lower alkoxy, difluoromethylenedioxyphenyl-group, (1-2) c-alkylenedioxyphenyl-group which is disubstituted with lower alkyl-methylenedioxyphenyl-group, pyridyl-group nonobligatory substituted with halogen or trifluoromethyl, naphthyl-group, thienyl-group nonobligatory substituted with halogen, furyl-group, methylindole-, methylpyrrol-group, indolyl-group, tetrahydronaphthyl or dihydrobenzofuryl-group. R4 H, lower alkyl nonobligatory substituted with halogen, cyclopropyl, lower alkoxy, methylthio or morpholino-group. A H, lower alkyl, halogen or lower alkoxy-group for exception when R′ methyl or ethyl. R″ H and ZR3 styrene-group. Also, fungicide composition is described that involves N-phenylcarbamate compound indicated above (0.2-75 wt.-%), and the special additions the rest up to 100 wt.-% EFFECT: improved method of synthesis. 3 cl, 3 tbl
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Authors
Dates
1995-12-10—Published
1992-02-06—Filed