FIELD: catalysts for organic syntheses. SUBSTANCE: invention relates to preparing improved catalysts for synthesis of carboxylic acid alkenyl esters from alkenes, carboxylic acids, and oxygen-containing gas. Catalysts contain palladium, gold, potassium promoter and are characterized by reduced content of sodium. The latter is achieved by (i) preparing catalyst using practically sodium-free reactants, (ii) washing catalyst with water or aqueous solution of potassium promoter after catalyst has been impregnated with the latter, and (iii) washing catalyst at a certain step of its preparation with cation-exchange solution. EFFECT: increased activity of catalyst. 2 cl, 4 dwg, 19 tbl
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Authors
Dates
1997-04-20—Published
1992-03-30—Filed