FIELD: processing of spent electrolytes used in deposition of copper coats on articles made of zirconium and its alloys, mechanical engineering and other branches of technology. SUBSTANCE: spent electrolytes containing copper vitriol, hydrofluoric acid and zirconium are treated with compositions of sodium ( sodium fluoride sulfate or their mixture ) with weight ratio Na:Zr as 1.15-1.19 followed by curing in the course of 2 h. Derived crystals are separated with subsequent correction of obtained solution. EFFECT: increased percentage of zirconium extracted from spent electrolytes and prevention of pollution of environment. 1 tbl
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METHOD OF REGENERATING NITRATE-FLUORIDE ZIRCONIUM-CONTAINING ETCHING SOLUTIONS | 1997 |
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METHOD FOR RECOVERING CHLORINE, FLUORINE FROM ANODE GAS AND WASTE ELECTROLYTE FORMED IN PROCESS FOR ELECTRODEPOSITION OF ZIRCONIUM | 1997 |
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METHOD OF PREPARING ZIRCONIUM FLUORIDE COMPOUNDS HAVING LOWER HAFNIUM CONTENT | 1999 |
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MOULDING METHOD OF PIPES FROM TITANIUM, ZIRCONIUM AND ITS ALLOYS | 2008 |
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METHOD FOR SEWAGE TREATMENT | 2003 |
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METHOD FOR ISOLATION OF COPPER SULFATE | 1994 |
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METHOD FOR PRODUCTION OF COPPER SULFATE | 1995 |
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METHOD OF TREATING COPPER AND SUPERCONDUCTIVE WIRE | 1998 |
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METHOD FOR REPROCESSING OF COPPER-CHLORIDE FUSION CAKE, WHICH IS WASTE FROM TITANIUM TETRACHLORIDE CLEANING | 2007 |
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Authors
Dates
1999-01-10—Published
1996-12-03—Filed