FIELD: industrial organic synthesis. SUBSTANCE: invention relates to production of chlorinated derivatives of methane, ethane, and ethylene by catalytic carbon tetrachloride hydrochlorination and is distinguished by that in platinum-on-carrier catalyst employed, as carrier for active component, diamond-like substance is utilized resulting in selectivity with respect to C2-compounds 2-8-fold higher than in known processes. EFFECT: increased selectivity. 1 tbl
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