FIELD: components of catalyst systems in processes of oligomerization and polymerization of olefins and diene hydrocarbons, more particularly fine organic and organometal synthesis. SUBSTANCE: method comprises reacting terminal acetylenes of general formula: R-≡, wherein R is н-C5H11, н-C6H13, Ph with dialkylamine aluminium dichlorides of general formula: 
wherein R′ is Et or n-Bu, and metallic magnesium in 10:(15-25):(12-16) molar ratio, respectively, in the presence of zirconacene dichloride in amount of 2-4 mole % with respect to acetylene. Reaction is carried out in argon atmosphere under normal conditions for 10-14 hours. Solvent is tetrahydrofuran. Yield of desired products is 56-74%. EFFECT: more efficient preparation method. 1 tbl
| Title |
Year |
Author |
Number |
| METHOD OF COMBINED PREPARATION OF 1-(DIALKYLAMINE)- 2,3,4,5-TETRAALKYL (ARYL) ALUMACYCLOPENTADIENES AND 1- (DIALKYLAMINE)-2,3-DIALKYL(ARYL) ALUMACYCLOPROPENES |
1997 |
- Dzhemilev U.M.
- Ibragimov A.G.
- Ramazanov I.R.
- Kunakova R.V.
- Khalilov L.M.
- Islamgulova A.Z.
- Sharipova A.Z.
|
RU2131432C1 |
| METHOD OF COMBINED SYNTHESIS OF 1-(ALKOXY)-2,4-DIALKYL(PHENYL)- -ALUMACYCLOPENTADIENS AND 1-(ALKOXY)-2-ALKYL(PHENYL)ALUMA- -CYCLOPROPENES |
1997 |
- Dzhemilev U.M.
- Ibragimov A.G.
- Jusupov Z.A.-Ja.
- Kunakova R.V.
- Khalilov L.M.
- Sharipova A.Z.
|
RU2131431C1 |
| METHOD OF COMBINED PREPARATION OF 1-(ALKOXY)-2,3,4,5- TETRAALKYL-(ARYL) ALUMACYCLOPENTADIENES AND 1-(ALKOXY)- 2,3-DIALKYL (ARYL)ALUMACYCLOPROPENES |
1997 |
- Dzhemilev U.M.
- Ibragimov A.G.
- Ramazanov I.R.
- Kunakova R.V.
- Khalilov L.M.
- Islamgulova A.Z.
- Sharipova A.Z.
|
RU2130024C1 |
| METHOD OF COMBINED PREPARATION OF 1-ETHYL-2,4-DIALKYL (ARYL)ALUMACYCLOPENTADIENES AND 1-ETHYL-2-ALKYL(ARYL) ALUMACYCLOPROPENES |
1997 |
- Dzhemilev U.M.
- Ibragimov A.G.
- Jusupov Z.A.-Ja.
- Khalilov L.M.
- Kunakova R.V.
- Sharipova A.Z.
|
RU2130026C1 |
| METHOD OF COMBINED PREPARATION OF 1-ETHYL-2,3,4,5- TETRAALKYL (ARYL) ALUMACYCLOPENTADIENES AND 1-ETHYL-2,3- DIALKYL(ARYL) ALUMACYCLOPROPENES |
1997 |
- Dzhemilev U.M.
- Ibragimov A.G.
- Ramazanov I.R.
- Islamgulova A.Z.
- Kunakova R.V.
- Khalilov L.M.
- Sharipova A.Z.
|
RU2130025C1 |
| METHOD OF COMBINED PREPARATION OF 1-(DIALKYLAMINE)-2,3- DIALKYL(PHENYL)ALUMACYCLOPROPENES, 1-(DIALKYLAMINE)-2,3- DIALKYL(PHENYL)ALUMACYCLOPENT-2-ENES AND 1- (DIALKYLAMINE)-2,3,4,5-TETRAALKYLALUMACYCLOPENTADIENES |
1999 |
- Dzhemilev U.M.
- Ibragimov A.G.
- Ramazanov I.R.
- Luk'Janova M.P.
- Chegodaeva M.F.
- Sharipova A.Z.
|
RU2157374C1 |
| METHOD OF OBTAINING OF 1-(DIALKYLAMINE)-3-ALKYLALUMACYCLOPENTANES |
1998 |
- Dzhemilev U.M.
- Ibragimov A.G.
- Khafizova L.O.
- Satenov K.G.
- Dodonova N.E.
- Kovtunenko I.A.
|
RU2139876C1 |
| CATALYST FOR SYNTHESIS OF 1-DIALKYLAMINE-2,3-DIPHENYLALUMA- -CYCLOPROPENES |
2000 |
- Dzhemilev U.M.
- Ibragimov A.G.
- Ramazanov I.R.
- Ajsuvakov I.Sh.
- Sultanov R.M.
- Kunakova R.V.
|
RU2175889C2 |
| METHOD OF COMBINED PREPARATION OF 1-ETHYL -2,3-DIACKYL (PHENYL)ALUMACYCLOPROPENES, 1-ETHYL-2,3-DIALKYL (PHENYL)ALUMACYCLOPENT-2-ENES AND 1-ETHYL-2,3,4,5-TETRAALYLALUMACYCLOPENTADIENES |
1999 |
- Dzhemilev U.M.
- Ibragimov A.G.
- Ramazanov I.R.
- Luk'Janova M.P.
- Dodonova N.E.
- Kovtunenko I.A.
|
RU2160269C1 |
| METHOD OF PREPARING 1-ALKOXY (OR DIALKYLAMINO)-2,3- DIPHENYL(ALKYL)ALUMACYCLOPROPENES |
1996 |
- Dzhemilev U.M.
- Ibragimov A.G.
- Ramazanov I.R.
- Khalimov L.M.
- Muslukhov R.R.
- Sultanov R.M.
|
RU2151772C1 |
