FIELD: chemical industry, more particularly fine organic, industrial and organometal synthesis. SUBSTANCE: present invention describes method of preparing new organoaluminium compounds of formula (1): 
and (2): 
. Method comprises reacting disubstituted acetylenes of formula: R-≡-R wherein R is p-Pr, p-Bu or Ph with alkoxyaluminium dichlorides of formula: RO′-AlCl2, wherein R′ is Et,n-Bu,CH2Ph and metallic magnesium in the presence of zirconacene dichloride catalyst in amount of 2-6 mole % with respect to disubstituted acetylene. Reaction is carried out argon atmosphere under normal condition. Solvent is diethyl ether and benzene. Reaction time is 16-24 hours. Yield of desired products is 48-70%. EFFECT: more efficient preparation method. 2 cl, 13 ex, 1 tbl
| Title |
Year |
Author |
Number |
| METHOD OF COMBINED SYNTHESIS OF 1-(ALKOXY)-2,4-DIALKYL(PHENYL)- -ALUMACYCLOPENTADIENS AND 1-(ALKOXY)-2-ALKYL(PHENYL)ALUMA- -CYCLOPROPENES |
1997 |
- Dzhemilev U.M.
- Ibragimov A.G.
- Jusupov Z.A.-Ja.
- Kunakova R.V.
- Khalilov L.M.
- Sharipova A.Z.
|
RU2131431C1 |
| METHOD OF COMBINED PREPARATION OF 1-(DIALKYLAMINE)- 2,3,4,5-TETRAALKYL (ARYL) ALUMACYCLOPENTADIENES AND 1- (DIALKYLAMINE)-2,3-DIALKYL(ARYL) ALUMACYCLOPROPENES |
1997 |
- Dzhemilev U.M.
- Ibragimov A.G.
- Ramazanov I.R.
- Kunakova R.V.
- Khalilov L.M.
- Islamgulova A.Z.
- Sharipova A.Z.
|
RU2131432C1 |
| METHOD OF COMBINED PREPARATION OF 1-ETHYL-2,3,4,5- TETRAALKYL (ARYL) ALUMACYCLOPENTADIENES AND 1-ETHYL-2,3- DIALKYL(ARYL) ALUMACYCLOPROPENES |
1997 |
- Dzhemilev U.M.
- Ibragimov A.G.
- Ramazanov I.R.
- Islamgulova A.Z.
- Kunakova R.V.
- Khalilov L.M.
- Sharipova A.Z.
|
RU2130025C1 |
| METHOD OF COMBINED PREPARATION OF 1-(DIALKYLAMINE)-2,4- DIALKYL(ARYL)ALUMACYCLOPENTADIENES AND 1-(DIALKYL-AMINE)- 2-ALKYL(ARYL)ALUMACYCLOPROPENES |
1997 |
- Dzhemilev U.M.
- Ibragimov A.G.
- Jusupov Z.A.-Ja.
- Khalilov L.M.
- Kunakova R.V.
- Sharipova A.Z.
|
RU2130027C1 |
| METHOD OF COMBINED PREPARATION OF 1-ETHYL-2,4-DIALKYL (ARYL)ALUMACYCLOPENTADIENES AND 1-ETHYL-2-ALKYL(ARYL) ALUMACYCLOPROPENES |
1997 |
- Dzhemilev U.M.
- Ibragimov A.G.
- Jusupov Z.A.-Ja.
- Khalilov L.M.
- Kunakova R.V.
- Sharipova A.Z.
|
RU2130026C1 |
| METHOD OF COMBINED PREPARATION OF 1-(ALKOXY)-2,3-DIALKYL (PHENYL)ALUMACYCLOPROPENES, 1-(ALKOXY)-2,3-DIALKYL(PHENYL)ALUMACYCLOPROPENT-2- ENES AND 1-(ALKOXY)-2,3,4,5-TETRAALKYLALUMACYCLOPENTADIENES |
1999 |
- Dzhemilev U.M.
- Ibragimov A.G.
- Ramazanov I.R.
- Luk'Janova M.P.
|
RU2160268C2 |
| CATALYST FOR 1-ALKOXY-2,3-DIPHENYLALUMACYCLOPROPENES PRODUCING |
2000 |
- Dzhemilev U.M.
- Ibragimov A.G.
- Ramazanov I.R.
- Ajsuvakov I.Sh.
- Sultanov R.M.
- Kunakova R.V.
|
RU2179477C2 |
| METHOD OF PREPARING 1-ALKOXY-3-ALKYLALUMACYCLPENTANES |
1998 |
- Dzhemilev U.M.
- Ibragimov A.G.
- Khafizova L.O.
- Satenov K.G.
- Sharipova A.Z.
- Kunakova R.V.
|
RU2139877C1 |
| METHOD OF PREPARING 1-ALKOXY (OR DIALKYLAMINO)-2,3- DIPHENYL(ALKYL)ALUMACYCLOPROPENES |
1996 |
- Dzhemilev U.M.
- Ibragimov A.G.
- Ramazanov I.R.
- Khalimov L.M.
- Muslukhov R.R.
- Sultanov R.M.
|
RU2151772C1 |
| METHOD OF COMBINED PREPARATION OF 1-ETHYL -2,3-DIACKYL (PHENYL)ALUMACYCLOPROPENES, 1-ETHYL-2,3-DIALKYL (PHENYL)ALUMACYCLOPENT-2-ENES AND 1-ETHYL-2,3,4,5-TETRAALYLALUMACYCLOPENTADIENES |
1999 |
- Dzhemilev U.M.
- Ibragimov A.G.
- Ramazanov I.R.
- Luk'Janova M.P.
- Dodonova N.E.
- Kovtunenko I.A.
|
RU2160269C1 |
