FIELD: ferrous metallurgy, winning of vanadium-carrying sludge during processing of blast furnace pig iron to steel. SUBSTANCE: process includes loading of metal scrap, pouring of pig iron, supply of limestone and fluorite followed by subsequent blow-through with oxygen. Magnesium-carrying addition in the amount ensuring content of magnesium within limits of 6.0-20.0% in vanadium-containing sludge is injected before loading of metal scrap. In the capacity of magnesium-carrying addition there are used magnesium carbonate powder and/or raw and burnt dolomite, dolomite and dunite mixture, iron-magnesium-calcium concentrate, breakage of forsterite-magnesium articles, etc. Proportion of magnesium-carrying material and metal scrap to amount of poured pig iron is established within bounds (0.0068-0.018): 1.0 and (0.21-0.23):1.0 correspondingly. Proposed process makes it possible to increase substantially resistance of lining of converter approximately 1.5-1.8 times and to win vanadium- carrying sludge with higher break-down of vanadium up to 76.8-80.5%. Besides, obtained sludge has considerably lower content of calcium and phosphorus oxides which results in decreased usage of reagents for hydrometallurgical processing. EFFECT: enhanced efficiency. 1 cl, 1 tbl
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PROCESS OF WINNING OF VANADIUM-CARRYING SLAG | 1998 |
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Authors
Dates
1999-06-10—Published
1998-03-25—Filed