FIELD: chemical industry. SUBSTANCE: method comprises contacting (a) liquid magnesium compound with (b) liquid titanium compound in the presence of organosilicon compound having inactive hydrogen in amount from 0.25 to 0.35 mole per 1 mole of magnesium compound (a), raising the resulting contact purging (i) temperature to 105-115 C and maintaining contact product at above-mentioned temperature. Contact product is then brought into contact with not more than 0.5 mole of organosilicon compound having inactive hydrogen (c). Also described is ethylene polymerization catalyst prepared from solid catalyst component and organometallic compound, and polymerization method using said catalyst. In using solid titanium catalyst component, ethylene is polymerized with high activities and ethylene polymer having superb particle properties is obtained. EFFECT: more efficient ethylene polymerization method. 5 cl, 1 dwg, 7 ex, 10 com. ex, 5 tbl
Title |
Year |
Author |
Number |
METHOD OF PREPARING SOLID TITANIUM CATALYTIC COMPONENT, OLEFIN- POLYMERIZATION CATALYST CONTAINING THEREOF, AND OLEFIN POLYMERIZATION PROCESS |
1996 |
- Kozhokh Shinichi
- Kioka Mamoru
|
RU2153932C2 |
SOLID TITANIUM CATALYST COMPONENT, OLEFIN POLYMERISATION CATALYST AND OLEFIN POLYMERISATION METHOD |
2008 |
- Matsunaga Kazukhisa
- Tsuru Kazutaka
- Kavakita Kazumitsu
- Sinozaki Tetsunori
|
RU2443715C1 |
SOLID TITANIUM COMPONENT OF OLEFIN POLYMERIZATION CATALYST, METHOD OF PREPARATION THEREOF, OLEFIN POLYMERIZATION CATALYST, AND OLEFIN POLYMERIZATION PROCESS |
1993 |
- Tetsua Toida
- Tetsunori Sinozaki
- Mamoru Kioka
|
RU2144041C1 |
PROPYLENE-BASED BLOCK COPOLYMER, COMPOSITION CONTAINING SAID BLOCK COPOLYMER AND MOULDED ARTICLES OBTAINED THEREFROM |
2009 |
- Matsunaga Katsukhisa
- Itakura Kejta
|
RU2463313C1 |
TITANIUM-CONTAINING COMPONENT OF CATALYST FOR ETHYLENE POLYMERIZATION, A CATALYST FOR ETHYLENE POLYMERIZATION AND A METHOD OF ETHYLENE POLYMERIZATION USING THIS CATALYST |
1993 |
- Mamoru Kioka[Jp]
- Tsuneo Jasiki[Jp]
|
RU2098428C1 |
SOLID COMPONENT OF TITANIUM CATALYST, OLEFIN POLYMERISATION CATALYST, OLEFIN POLYMERISATION METHOD AND PROPYLENE POLYMER |
2021 |
- Kimura Takashi
- Isogai Makoto
- Nakayama Yasushi
- Mitsiue Keni
- Jinnai Takashi
- Yamada Vataru
- Takano Shotaro
- Terao Khiroshi
- Yano Takaaki
- Totani Eshiyuki
- Moorti Sunil Krzisztof
- Nakano Takashi
|
RU2825733C1 |
METHOD OF PREPARING ALPHA-OLEFIN (CO) POLYMERS |
1991 |
- Mamoru Kioka[Jp]
- Noris Kasiva[Jp]
|
RU2091393C1 |
SOLID COMPONENT OF ALPHA-OLEFIN POLYMERIZATION CATALYST, ALPHA-OLEFIN POLYMERIZATION CATALYST, AND METHOD OF PREPARATION OF POLYOLEFINS |
1990 |
- Mamoru Kioka[Jp]
- Masao Nakano[Jp]
- Takasi Ueda[Jp]
|
RU2092495C1 |
ETHYLENE RESIN COMPOSITION FOR BLOW MOULDING AND ARTICLES BLOW MOULDED FROM SAID COMPOSITION |
2008 |
- Khirase Josijuki
- Ivamasa Kendzhi
|
RU2434898C2 |
SUPPORTED ETHYLENE (CO) |
2000 |
- Lo Khehkuan'
- Tan Zhujgo
- Jan Khua
- Chzhao Tsin'Fan
|
RU2258711C2 |