FIELD: polymerization catalysts and processes. SUBSTANCE: invention relates to synthesis of polyolefins in presence of high- efficiency HOMOGENEOUS catalytic systems based on IVB-group metallocene complexes and organoaluminum compounds. Catalytic system in question is dialkyl bis(2-arylindenyl) complexes of IVB-group metals and trialkylaluminum at Al/M ratio from 50 to 500. Basically new two-component catalytic system allows one to use low concentrations of metallocene complexes. EFFECT: increased catalytic activity.
| Title |
Year |
Author |
Number |
| COMPLEX ORGANOMETALLIC PROPYLENE POLYMERIZATION CATALYST AND METHOD FOR PRODUCTION OF ELASTOMER STEREOBLOCK POLYPROPYLENE |
2004 |
- Dzhabieva Zinaida Mikhajlovna
- Topilin Sergej Vasil'Evich
- Kuznetsova Svetlana Aleksandrovna
- Dzhabiev Tejmuraz Savel'Evich
- Atovmjan Lev Oganovich
- Aldoshin Sergej Mikhajlovich
|
RU2275380C2 |
| HOMOGENEOUS CATALYTIC SYSTEM FOR SYNTHESIS OF LOW-MOLECULAR BRANCHED POLYETHYLENE AND METHOD OF PREPARING LOW-MOLECULAR BRANCHED POLYETHYLENE |
1999 |
- Bravaja N.M.
- Panin A.N.
- Babkina O.N.
- Karpova N.D.
|
RU2161628C1 |
| IMMOBILIZED CATALYST FOR MONO-AND COPOLYMERIZATION OF OLEFINS, METHOD OF PREPARING THEREOF AND METHOD OF PREPARING HOMO-AND COPOLYMERS OF OLEFINS |
1999 |
- Bravaja N.M.
- Chukanova O.M.
- Saratovskikh S.L.
- Babkina O.N.
- Panin A.N.
|
RU2171814C1 |
| METHOD OF PREPARING STEREOREGULAR POLYPROPYLENE |
1999 |
- Nedorezova P.M.
- Tsvetkova V.I.
- Aladyshev A.M.
- Savinov D.V.
- Kljamkina A.N.
- Lemenovskij D.A.
- Brusova G.P.
- Veksler Eh.N.
|
RU2154070C1 |
| HOMOGENOUS CATALYTIC SYSTEM FOR SYNTHESIS OF COPOLYMERS OF ETHYLENE WITH PROPYLENE AND HIGHER α-OLEFINS AND ALSO PROPYLENE WITH HIGHER α-OLEFINS, METHOD OF PRODUCING COPOLYMERS OF ETHYLENE WITH PROPYLENE AND HIGHER α-OLEFINS AND ALSO PROPYLENE WITH HIGHER α-OLEFINS |
2003 |
|
RU2250237C2 |
| METHOD OF PRODUCING COPOLYMERS OF OLEFIN MONOMERS WITH CYCLIC OR LINEAR DIENES |
2011 |
- Bravaja Natal'Ja Mikhajlovna
- Panin Andrej Nikolaevich
|
RU2477289C1 |
| CATALYTIC METALLOCENE SYSTEM FOR SYNTHESIS OF POLYOLEFINS, CONTAINING LEWIS BASES, METHOD OF OBTAINING POLYOLEFINS ON CATALYTIC SYSTEM, CONTAINING LEWIS BASES |
2006 |
- Bravaja Natal'Ja Mikhajlovna
- Sanginov Evgenij Aleksandrovich
- Panin Andrej Nikolaevich
- Babkina Ol'Ga Nikolaevna
- Saratovskikh Stanislav L'Vovich
|
RU2338755C2 |
| USE OF ARYL OXIDES OF ISOBUTYL ALUMINIUM AS ACTIVATORS DIALKYL METALLOCENE CATALYSTS FOR HOMOPOLYMERISATION ETHYLENE, PROPYLENE, COPOLYMERISATION OF ETHYLENE WITH PROPYLENE AND TRIPLE COPOLYMERISATION OF ETHYLENE, PROPYLENE AND DIENE, HOMOGENEOUS METALLOCENE CATALYST SYSTEMS FOR SYNTHESIS OF HOMO-AND COPOLYMERS OF OLEFINS AND DIENES, METHOD OF PRODUCING HOMO- AND COPOLYMERS OF OLEFINS AND DIENES, METHOD FOR STABILISATION OF HOMO- AND COPOLYMERS OF OLEFINS AND DIENES |
2014 |
- Fajngold Evgenij Efimovich
- Bravaya Natalya Mikhajlovna
- Panin Andrej Nikolaevich
- Saratovskikh Stanislav Lvovich
- Babkina Olga Nikolaevna
|
RU2588496C2 |
| METHOD OF PREPARING HEAT- AND ELECTROCONDUCTIVE MATERIAL, AND MATERIAL PREPARED BY THIS METHOD |
2001 |
- Nedorezova P.M.
- Shevchenko V.G.
- Kljamkina A.N.
- Monakhova T.V.
- Tsvetkova V.I.
- Lemenovskij D.A.
|
RU2200170C1 |
| ANSSA-ZIRCONOCENES FUNCTIONED WITH RESPECT TO CYCLOSILANE BRIDGES, AND METHOD OF PREPARATION THEREOF |
1999 |
- Lemenovskij D.A.
- Krut'Ko D.P.
- Borzov M.V.
- Brusova G.P.
- Veksler Eh.N.
- Nedorezova P.M.
- Tsvetkova V.I.
|
RU2160277C1 |
