FIELD: polymer production. SUBSTANCE: vinylidene fluoride-based polymers are prepared via water-emulsion polymerization of vinylidene fluoride or copolymerization of vinylidene fluoride with perfluorinated vinyl monomer initiated by betahydroxyethyl- tert-butyl peroxide at 86-98 C and pressure 2.5 MPa in presence of surfactant and formic acid, monomers in reaction medium being fed additionally as the process advances. Peroxide is added to reaction medium before beginning of polymerization process in amounts 0.001 to 0.01% of the weight of water. EFFECT: enabled production of polymers within a wide condition range with high yield of product per unit of volume of reactor. 6 cl, 2 tbl, 13 ex
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Authors
Dates
2003-03-10—Published
2001-07-24—Filed