FIELD: polymers, in particular method for production of tetrafluoroethylene copolymers.
SUBSTANCE: tetrafluoroethylene copolymers with hexafluoropropylene and perfluoroalkylvinyl ester are obtained by copolymerization of said monomers in liquid medium in presence of radical initiator at elevated temperature and pressure. Charged monomer mixture contains (mol %): tetrafluoroethylene 18.75-54.5, hexafluoropropylene 17-66.75, and perfluoroalkylvinyl ester 7.8-28.5. Additional feeding is carried out by using monomer mixture containing (mol %): tetrafluoroethylene 76-90, hexafluoropropylene 5-12, and perfluoroalkylvinyl ester 5-12. Method of present invention makes it possible to inhibit copolymerization without losses of high efficiency and to produce copolymer with constant desired composition.
EFFECT: copolymer with increased elasticity, high resistance at elevated temperature and decreased reprocessing temperature.
3 cl, 10 ex, 2 tbl
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Authors
Dates
2005-05-10—Published
2003-10-22—Filed