FIELD: organic chemistry, chemical technology. SUBSTANCE: invention relates to method for preparing carbonyl compounds with number of atoms C2-C40. Method involves reaction of liquid-phase oxidation of aliphatic C2-C40-alkenes of the formula (I): wherein R1, R3, R3, R4 are radicals that can be represented by hydrogen atoms, alkyl, alkenyl or aryl radicals, among them comprising functional groups, except for radicals that comprise non-aromatic carbocycles having double bonds C=C to carbonyl compounds with nitrous oxide in the presence of inert gas as a diluting agent at temperature 100-350 C and under pressure of nitrous oxide 1.5-100 atm. Process provides the high selectivity by end products, explosion-proofing and shows outlook for industrial using. EFFECT: improved preparing method. 5 cl, 3 tbl, 25 ex
Title | Year | Author | Number |
---|---|---|---|
METHOD FOR PREPARING SUBSTITUTED MONOCYCLIC KETONES | 2002 |
|
RU2227134C2 |
METHOD FOR PREPARING MONOCYCLIC C-C-KETONES | 2002 |
|
RU2227136C2 |
METHOD FOR PREPARING CYCLOPENTANONE | 2002 |
|
RU2227135C2 |
CYCLOHEXANONE PRODUCTION PROCESS | 2002 |
|
RU2205175C1 |
METHOD OF PRODUCING DERIVATIVES OF 1-PYRAZOLINA | 2015 |
|
RU2598077C1 |
METHOD FOR PRODUCTION OF CARBONYL COMPOUNDS | 2004 |
|
RU2270185C1 |
METHOD OF PREPARING POLYMERS CONTAINING FUNCTIONAL GROUPS | 2004 |
|
RU2283849C2 |
METHOD OF INTRODUCING CARBONYL GROUPS INTO POLYMERS | 2003 |
|
RU2230754C1 |
METHOD OF PRODUCTION OF THE POLYMERIC COMPOUNDS AND THE OLIGOMERS CONTAINING THE FUNCTIONAL GROUPS | 2004 |
|
RU2280044C1 |
METHOD FOR MODIFYING POLYMER COMPRISING DOUBLE CARBON-CARBON BONDS | 2003 |
|
RU2235102C1 |
Authors
Dates
2004-04-20—Published
2002-03-20—Filed