FIELD: nuclear fuel recovery. SUBSTANCE: method includes bringing Np(VI) containing organic phase in contact with oxime of R2C=NOH formula. Each R independently means H or organic substituent. Method also includes bringing U, Pu, and Np containing organic phase in contact with oxime of formula R2C=NOH, where each R independently means H or organic substituent. Oxime reduces Pu(IV) to Pu(III) and Np(VI) to Np(V) and Pu(III).Oxime of formula R2C=NOH is used for reducing Np(VI) to Np(V). Oxime of formula R2C=NOH is used to reduce Pu(IV) to Pu(III). Oxime of formula R2C=NOH is used for joint reduction of Np(VI) to NP(V) and Pu(IV) to Pu(III). EFFECT: enhanced efficiency of uranium separation from plutonium and neptunium. 19 cl, 1 dwg, 5 tbl, 3 ex
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Authors
Dates
2004-05-20—Published
1998-08-20—Filed