FIELD: organic chemistry, chemical technology.
SUBSTANCE: invention relates to new P,N-bidentate ligands of the formula (I):
wherein A represents sulfur atom (S) or NR wherein R represents (C1-C4)-alkyl; R1 and R2 represent hydrogen atom, (C1-C4)-alkyl or R1 and R2 can be cyclizated to form benzene ring; R3 and R4 represent (C1-C4)-alkyl or phenyl; R5 and R6 represent (C1-C4)-alkyl. Indicated compounds can be used as components of catalysts in reactions of amination, cross-coupling, hydroformylation, allyl alkylation and others.
EFFECT: improved preparing method.
2 cl, 1 tbl, 3 ex
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Year |
Author |
Number |
| NEW ACHIRAL DIPHOSPHINE LIGAND, COMPLEXES BASED ON THEREOF AND METHOD FOR ITS PREPARING |
2002 |
- Nifant'Ev I.Eh.
- Chevykalova M.N.
|
RU2225412C2 |
| METALLOCENE COMPOUND, LIGAND, METHODS FOR PREPARING LIGAND, CATALYST, METHOD FOR PREPARING ALPHA-OLEFINS POLYMER, PROPYLENE HOMOPOLYMER, PROPYLENE COPOLYMER |
2000 |
- Nifant'Ev I.E.
- Guidotti Simona
- Reskoni Luidzhi
- Lajshevtsev I.P.
|
RU2243229C2 |
| ANSSA-ZIRCONOCENES FUNCTIONED WITH RESPECT TO CYCLOSILANE BRIDGES, AND METHOD OF PREPARATION THEREOF |
1999 |
- Lemenovskij D.A.
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- Brusova G.P.
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- Tsvetkova V.I.
|
RU2160277C1 |
| METHOD |
2014 |
- Fakketti Sara
- Nedden Khans
|
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| HETEROARYL-ARYLDIPHOSPHINES AND METHOD FOR THEIR PREPARING |
2002 |
- Nifant'Ev I.Eh.
- Chevykalova M.N.
- Artemova N.V.
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RU2223965C1 |
| METAL-ORGANIC COMPOUND OF TRANSITIVE METAL, BISCYCLOPENTADIENYL LIGAND SYSTEM, CATALYST SYSTEM AND OBTAINING OF POLYOLEFINS |
2004 |
- Okumura Josikuni
- Nifant'Ev Il'Ja Ehduardovich
- Ehlder Majkl
- Ivchenko Pavel Vasil'Evich
- Bagrov Vladimir Vladimirovich
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RU2362779C2 |
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2001 |
- Reskoni Luidzhi
- Gvidotti Simona
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RU2248980C2 |
| METHOD OF SYNTHESIS OF BRIDGE METALLOCENE COMPOUND, BRIDGE BIS-CYCLOPENTADIENYL LIGAND |
1996 |
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- Reskoni Luidzhi(It)
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RU2168515C2 |
| DIPHOSPHINE AND METAL COMPLEXES |
2006 |
- Kessel'Gruber Martin
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| CATALYST SYSTEM |
2005 |
- Istkhehm Grehkham
- Tindehjl Nil
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RU2372989C2 |
