FIELD: precious metals technology.
SUBSTANCE: method comprises treatment of initial material with reagent solution under microwave irradiation to transfer precious metals into solution. Initial material is preliminarily subjected to mechanical activation during 5 to 120 min while maintaining ratio of mechanical power supplied to specific surface area of activated material within a range of 0.0133 to 25 W-kg·m2. Microwave treatment starts directly after mechanical activation using acid and/or oxidant to form slurry from activated material and reagent solution. Irradiation is carried out to boiling temperature. Acid and/or oxidant is selected from HCl and/or Cl2, HCl and/or H2O, HCl and/or Br2, HCl and/or NaClO3, HCl and/or HNO3, HF and HCl and/or NaClO3, mixtures of H2SO4 and HCl and/or H2O2, mixtures of HCl and HBr and/or H2O2, mixtures of HCl and HI and/or NaClO3 and J2, HCl and/or Cl2 and Br2.
EFFECT: increased degree of precious metal recovery.
3 cl, 13 ex
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Authors
Dates
2005-02-27—Published
2003-05-07—Filed