FIELD: organic chemistry, chemical technology.
SUBSTANCE: invention relates to a method for preparing a photo- and thermostabilizer for preparing weatherproof polyethylene. Method for preparing photo- and thermostabilizer involves heating 2-tert.-butylphenol and methanol in autoclave in the presence of alkali and zinc oxide at temperature 220-250°C and prepared product represents a mixture comprising tert.-butylated hydroxy-exo-calyx[4]arenes and methylene-bis-phenols. For stabilizing high density polyethylene the use of a mixture of tert.-butylated hydroxy-exo-calyx[4]arenes and methylene-bis-phenols taken in the amounts 0.25-0.5% is the most effective. Photo- and thermostabilizer are prepared for a single stage by using available taw. Photo- and thermostabilizers of weatherproof polyethylene represents a mixture of tert.-butylated hydroxy-exo-calyx[4]arenes and methylene-bis-phenols and provides more effective photo- and thermostabilization as compared with using individual products as stabilizers.
EFFECT: improved preparing method.
2 tbl, 1 dwg
Title | Year | Author | Number |
---|---|---|---|
LIQUID MIXTURES OF PHOSPHATES AS STABILISERS | 2007 |
|
RU2455325C2 |
HYDROGENATED POLYMERS WITH RADIAL STRUCTURE HAVING CORE BASED ON CALIXARENES AND USE THEREOF IN LUBRICANT COMPOSITIONS | 2015 |
|
RU2672421C2 |
UNCOLORING STABILIZER FOR SYNTHETIC RUBBERS | 1996 |
|
RU2124532C1 |
STABILISING MIXTURE FOR HIGH CHLORINE RESISTANCE | 2006 |
|
RU2408617C2 |
METHOD OF PREPARING STERICALLY-HINDERED BIS- OR POLYPHENOLS | 0 |
|
SU732232A1 |
METHOD OF DETECTING REAGENT, POLYMER, ELECTRODE PASTE, ELECTRODE, AND CALYXARENE | 1994 |
|
RU2133463C1 |
DERIVATIVES OF BENZOFURAN-2-ONES, STABILIZED COMPOSITION, METHOD OF STABILIZATION, DERIVATIVES OF MANDELIC ACID AND METHOD OF THEIR SYNTHESIS | 1993 |
|
RU2130931C1 |
SPACE-HINDERED BIS-PHENOL PRODUCTION PROCESS | 2001 |
|
RU2195444C1 |
OLIGOMEROUS COMPOUNDS, COMPOSITION, METHOD OF STABILIZATION AND OLIGOMEROUS COMPOUNDS | 1993 |
|
RU2130461C1 |
PRODUCTS OF OLIGOMERIZATION OF 10-PROPENYL PHENOTHIAZINE AS STABILIZING AGENT FOR POLYOLEFINS | 1995 |
|
RU2100360C1 |
Authors
Dates
2005-11-27—Published
2004-01-19—Filed