FIELD: chemical technology.
SUBSTANCE: invention relates to a method for preparing fluorine atom-containing sulfonylfluoride compound. Method involves interaction of compound of the following formula (1a): XSO2RA-CH2OH with compound of the following formula (2a): RB-COY to form compound of the formula (3a): XSO2RA-CH2OCO-RB followed by interaction of compound of the formula (3a) with fluorine in liquid phase to form compound of the following formula (4a): FSO2RAF-CF2OCO-RBF and the following decomposition of compound of the formula (4a) in the presence of a nucleophilic agent to form compound of the following formula (5a): FSO2RAF-COF. Synthesized compounds can be used as materials for making ion-exchange membranes. Method provides preparing compound of the formula (4a) without structural limitations and in combination with low cost of the process.
EFFECT: improved preparing method.
7 cl, 6 ex
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Authors
Dates
2006-06-27—Published
2001-11-28—Filed