FIELD: industrial organic synthesis.
SUBSTANCE: invention relates to composition suitable for use in reaction zone wherein aniline is brought into contact with nitrobenzene to produce 4-aminodiphenylamine synthesis intermediates, which composition contains zeolite having internal channels with a base introduced therein to take part in above reaction. Dimensions of cross-section of channels is such that a limited reaction transition state is ensured thereby improving selectivity of reaction with regard to desired intermediates. Invention also related to the title process using above defined composition.
EFFECT: improved selectivity of 4-aminodiphenylamine intermediates production.
9 cl, 12 dwg, 7 tbl, 8 ex
Title | Year | Author | Number |
---|---|---|---|
METHOD FOR PREPARING 4-AMINODIPHENYLAMINE AND ITS INTERMEDIATE COMPOUNDS | 2003 |
|
RU2289569C2 |
METHOD FOR PREPARING 4-AMINODIPHENYLAMINES | 2002 |
|
RU2280640C2 |
CATALYTIC HYDROGENATION OF NITROBENZENE TO 4-AMINODIPHENYLAMINE | 1998 |
|
RU2213088C2 |
METHOD OF PREPARING 4-NITRO AND/OR 4-NITROSODIPHENYL AMINE, METHOD OR PREPARING 4-AMINODIPHENYL AMINE DERIVATIVES, AND METHOD OF PREPARING ALKYLATED P- PHENYLENE DIAMINE DERIVATIVES | 1992 |
|
RU2102381C1 |
METHOD OF NITRATION OF BENZENE | 1994 |
|
RU2087463C1 |
PRODUCTION OF AROMATIC COMPOUNDS FROM METHANE | 2008 |
|
RU2491120C2 |
OBTAINING AROMATIC COMPOUNDS FROM METHANE | 2009 |
|
RU2514915C2 |
CATALYST FOR PYROLYSIS OF FEEDSTOCK | 2015 |
|
RU2684108C2 |
METHOD OF OBTAINING DIAMINODIPHENYLMETAHE AND ITS HIGHEST HOMOLOGUES | 2003 |
|
RU2330016C2 |
4-AMINODIPHENYLAMINE PRODUCTION PROCESS | 1999 |
|
RU2224741C2 |
Authors
Dates
2006-07-27—Published
2001-06-20—Filed