FIELD: polymers, rubber industry, in particular production of stereoblock polymers of conjugated dienes, such as cis-1,4-polyisoprene.
SUBSTANCE: modified cis-1,4-polyisoprene is obtained by polymerization pf isoprene in isopentane medium in presence of Ziegler-Natta catalyst. Then catalyst is deactivated; polymer is stabilized and modified with nitrogen-containing compound; polymer in isolated and dried. As nitrogen-containing compound reaction product of maleic anhydride and N-alkyl-N'-phenyl-n-phenylenediamine in amount of 0.5-2 % based on polymer is used.
EFFECT: simplified method for production of polymers having heat oxidative stability.
1 tbl, 1 ex
Title | Year | Author | Number |
---|---|---|---|
METHOD OF PRODUCING MODIFIED CIS-1,4-POLYISOPRENE | 2012 |
|
RU2532179C2 |
METHOD OF OBTAINING MODIFIED CIS-1,4-POLYISOPRENE | 2012 |
|
RU2527083C2 |
METHOD OF PRODUCING MODIFIED CIS-1,4-POLYISOPRENE | 2007 |
|
RU2352588C2 |
MODIFIED CIS-1,4-POLYISOPRENE PRODUCING METHOD | 2015 |
|
RU2595138C1 |
METHOD FOR PREPARING MODIFIED CIS-1,4-POLYISOPRENE | 2002 |
|
RU2206579C1 |
METHOD OF OBTAINING MODIFIED CIS-1,4-POLYISOPRENE | 0 |
|
SU675870A1 |
METHOD OF OBTAINING MODIFIED CIS-1,4-POLYISOPRENE BY ISOPRENE POLYMERIZATION | 0 |
|
SU866983A1 |
METHOD OF OBTAINING MODIFIED CIS 1,4-POLYISOPRENE | 0 |
|
SU788676A1 |
METHOD FOR OBTAINING MODIFIED CIS-1,4-POLYISOPRENE | 0 |
|
SU1666464A1 |
METHOD FOR PRODUCTION OF SYNTHETIC POLYISOPRENE | 1992 |
|
RU2067983C1 |
Authors
Dates
2006-08-10—Published
2005-02-22—Filed