FIELD: chemistry.
SUBSTANCE: invention relates to production of conjugated dienes stereoregular polymers and can be used in the synthetic rubber industry, in tyre and rubber industry. Described is a method of modified CIS-1,4-polyisoprene producing in organic solvent in the presence of complex organometallic catalyst. Method includes stabilization, separating, drying and modification. Modification is carried out at drying stage using monoester of maleic acid mixed with diisopropylxanthogen disulfide. Diisopropylxanthogen disulfide is taken in amount of 5-10 wt% of maleic acid ester weight, and maleic acid monoester is in amount of 0.2-2.0 wt% from polymer weight.
EFFECT: technical result is higher cohesion strength of raw rubber mixtures based on modified polymer and tear resistance of vulcanised rubber.
1 cl, 2 tbl, 5 ex
Title | Year | Author | Number |
---|---|---|---|
METHOD OF PRODUCING MODIFIED CIS-1,4-POLYISOPRENE | 2007 |
|
RU2352588C2 |
METHOD OF OBTAINING MODIFIED CIS 1,4-POLYISOPRENE | 0 |
|
SU788676A1 |
METHOD OF PRODUCING MODIFIED CIS-1,4-POLYISOPRENE | 2012 |
|
RU2532179C2 |
METHOD FOR PRODUCTION OF MODIFIED CIS-1,4-POLYISOPRENE | 2005 |
|
RU2281295C1 |
METHOD OF OBTAINING MODIFIED CIS-1,4-POLYISOPRENE | 0 |
|
SU675870A1 |
METHOD OF OBTAINING MODIFIED CIS-1,4-POLYISOPRENE BY ISOPRENE POLYMERIZATION | 0 |
|
SU866983A1 |
METHOD FOR PRODUCTION OF SYNTHETIC POLYISOPRENE | 1992 |
|
RU2067983C1 |
METHOD OF OBTAINING MODIFIED CIS-1,4-POLYISOPRENE | 0 |
|
SU675871A1 |
METHOD OF OBTAINING MODIFIED CIS-1,4-POLYISOPRENE | 2012 |
|
RU2527083C2 |
METHOD FOR PRODUCTION OF MODIFIED POLYISOPRENE COMPOSITION AND RUBBER COMPOUND UTILIZING IT | 2002 |
|
RU2215751C1 |
Authors
Dates
2016-08-20—Published
2015-02-24—Filed