FIELD: chemistry.
SUBSTANCE: invention relates to field of obtaining polymers of conjugated dienes, in particular, to obtaining modified cis-1,4-polyisoprene. Isoprene polymerisation in presence of catalyst is carried out with further catalyst deactivation, stabilisation and modification of polymer by product of interaction of maleic anhydride and N-alkyl- N′-phenyl-n-phenylenediamine, taken in weight ratio 15-30:70-85. After that, degassing and drying of polymer are performed. Before degassing, suspension of fullerene soot in organic solvent in amount 0.009-0.12 wt % of dry substance counted for polymer is introduced into polymerisate.
EFFECT: method makes it possible to obtain modified cis-1,4-polyisoprene, which used as base for vulcanisates contributes to their improved frost resistance with preservation of good physical-mechanical parameters.
1 tbl, 1 ex
Title | Year | Author | Number |
---|---|---|---|
METHOD OF PRODUCING MODIFIED CIS-1,4-POLYISOPRENE | 2012 |
|
RU2532179C2 |
METHOD FOR PRODUCTION OF MODIFIED CIS-1,4-POLYISOPRENE | 2005 |
|
RU2281295C1 |
METHOD OF PRODUCING MODIFIED CIS-1,4-POLYISOPRENE | 2007 |
|
RU2352588C2 |
MODIFIED CIS-1,4-POLYISOPRENE PRODUCING METHOD | 2015 |
|
RU2595138C1 |
METHOD FOR PREPARING MODIFIED CIS-1,4-POLYISOPRENE | 2002 |
|
RU2206579C1 |
METHOD FOR PRODUCTION OF MODIFIED POLYISOPRENE COMPOSITION AND RUBBER COMPOUND UTILIZING IT | 2002 |
|
RU2215751C1 |
METHOD OF PREPARING CIS-1, 4-POLYISOPRENE RUBBER | 0 |
|
SU587138A1 |
METHOD OF PREPARING STABILIZER AND POLYISOPRENE COMPOSITION CONTAINING THEREOF | 2002 |
|
RU2224769C2 |
METHOD OF OBTAINING MODIFIED CIS-1,4-POLYISOPRENE | 0 |
|
SU675871A1 |
METHOD OF PREPARING POLYMERIC AMINE ANTIOXIDANT | 1996 |
|
RU2130033C1 |
Authors
Dates
2014-08-27—Published
2012-09-04—Filed