METHOD OF OBTAINING MODIFIED CIS-1,4-POLYISOPRENE Russian patent published in 2014 - IPC C08C19/22 C08F36/08 C08F136/08 

Abstract RU 2527083 C2

FIELD: chemistry.

SUBSTANCE: invention relates to field of obtaining polymers of conjugated dienes, in particular, to obtaining modified cis-1,4-polyisoprene. Isoprene polymerisation in presence of catalyst is carried out with further catalyst deactivation, stabilisation and modification of polymer by product of interaction of maleic anhydride and N-alkyl- N′-phenyl-n-phenylenediamine, taken in weight ratio 15-30:70-85. After that, degassing and drying of polymer are performed. Before degassing, suspension of fullerene soot in organic solvent in amount 0.009-0.12 wt % of dry substance counted for polymer is introduced into polymerisate.

EFFECT: method makes it possible to obtain modified cis-1,4-polyisoprene, which used as base for vulcanisates contributes to their improved frost resistance with preservation of good physical-mechanical parameters.

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RU 2 527 083 C2

Authors

Solodkij Valentin Valentinovich

Bratsykhin Jurij Jur'Evich

Matveeva Larisa Jur'Evna

Kurljand Sergej Karlovich

Dates

2014-08-27Published

2012-09-04Filed