FIELD: organic synthesis catalysts.
SUBSTANCE: invention relates to a process for preparing catalyst, to catalyst prepared by this process, and to alkenyl carboxylate production process involving reaction of mixture containing olefin, carboxylic acid, and oxygen in presence of catalyst. Catalyst preparation process comprises following stages: (i) providing silica-based carrier subjected to a series of washings with one or several aqueous liquids with pH at least 3 (20°C) or silica-based carrier formed from materials, one or several of them were subjected to indicated series of washings; (ii) precipitating group VIII metal onto carrier; (iii) transforming precipitates group VIII metal into metal particles; and (iv) treating combination group VIII metal/carrier to purify it before or after stage (iii).
EFFECT: stabilized activity and selectivity of catalyst over a long period of time.
14 cl, 7 ex
Title | Year | Author | Number |
---|---|---|---|
VINYL ACETATE-SYNTHESIS CATALYST CONTAINING PALLADIUM, GOLD, COPPER, AND A CERTAIN FOURTH METAL | 1998 |
|
RU2202411C2 |
LAYERED CARRIER MATERIAL FOR CATALYST | 2004 |
|
RU2380154C2 |
METHOD OF PRODUCING CATALYSTS AND THEIR APPLICATION FOR OXIDISING OLEFINS IN VAPOR PHASE | 2007 |
|
RU2447939C2 |
MODIFIED CARRIER MATERIALS FOR CATALYSTS | 2005 |
|
RU2422433C2 |
METHOD OF PRODUCING CATALYST FOR SYNTHESIS OF VINYL ACETATE | 2009 |
|
RU2422201C1 |
METHOD OF CATALYST PREPARATION | 2015 |
|
RU2710375C2 |
CATALYST PRECURSORS NOT CONTAINING HALIDES | 2004 |
|
RU2397017C2 |
CATALYSTS | 2011 |
|
RU2551433C1 |
METHOD OF PREPARING CATALYST FOR PRODUCTION OF VINYL ACETATE INCLUDING PALLADIUM AND GOLD ON COPPER-CONTAINING SUPPORT, AND METHOD FOR PRODUCTION OF VINYL ACETATE USING ABOVE CATALYST (OPTIONS) | 1998 |
|
RU2198731C2 |
RHODIUM-CONTAINING CATALYSTS | 2004 |
|
RU2378047C2 |
Authors
Dates
2006-08-27—Published
2002-03-28—Filed