FIELD: organic synthesis catalysts.
SUBSTANCE: invention relates to methods for preparing catalyst precursors and group VIII metal-based catalysts on carrier, and to a process of producing hydrocarbons from synthesis gas using catalyst of invention. Preparation of precursor of group VIII metal-based catalyst comprises: (i) imposing mechanical energy to mixture containing refractory oxide, combining catalyst precursor with water to form paste comprising at least 60 wt % of solids, wherein ratio of size of particles present in system in the end of stage (i) to that in the beginning of stage (i) ranges from 0.02 to 0.5; (ii) mixing above prepared paste with water to form suspension containing no more than 55% solids; (iii) formation and drying of suspension from stage (ii); and (iv) calcination. Described are also method of preparing group VIII metal-based catalyst using catalyst precursor involving reduction reaction and process for production of hydrocarbons by bringing carbon monoxide into contact with hydrogen are elevated temperature and pressure in presence of above-prepared catalyst.
EFFECT: increased catalytic activity and selectivity.
12 cl, 1 tbl, 3 ex
Title | Year | Author | Number |
---|---|---|---|
CRUSTED METALLIC CATALYST, METHOD FOR PREPARATION THEREOF, AND A HYDROCARBON PRODUCTION PROCESS | 2001 |
|
RU2271250C2 |
METHOD OF PRODUCTION OF THE CATALYST AND THE METHOD OF PRODUCTION OF HYDROCARBONS WITH USAGE OF THE CATALYST | 2001 |
|
RU2286211C2 |
METHOD FOR PREPARING HYDROCARBON AND CATALYST FOR ITS REALIZATION | 2001 |
|
RU2266884C2 |
METHOD OF CATALYST PREPARATION | 2015 |
|
RU2710375C2 |
METHOD OF PRODUCING HYDROCARBON SYNTHESIS CATALYST | 2006 |
|
RU2412001C2 |
ELONGATED MOLD PARTICLES; THEIR APPLICATION AS CATALYST OR CATALYST CARRIER | 2003 |
|
RU2326734C2 |
CATALYST AND METHOD FOR PREPARING HYDROCARBONS | 2001 |
|
RU2259988C2 |
PROCESS FOR PRODUCTION OF HYDROCARBONS FROM CARBON MONOXIDE AND HYDROGEN | 2001 |
|
RU2273515C2 |
METHOD OF PRODUCTION OF CARRIER FOR CATALYST USED IN HYDROCARBONS SYNTHESIS, AND A METHOD OF CATALYST PRODUCTION FOR HYDROCARBONS SYNTHESIS | 1990 |
|
RU2007215C1 |
METHOD OF OBTAINING CARRIER FOR CATALYST WITH HIGHER STABILITY (VERSIONS), CATALYST FOR SYNTHESIS OF HYDROCARBONS AND METHOD OF HYDROCARBONS SYNTHESIS FROM SYNTHESIS-GAS | 2003 |
|
RU2340394C2 |
Authors
Dates
2006-08-27—Published
2001-07-10—Filed