FIELD: organic chemistry, chemical technology.
SUBSTANCE: invention relates to the improved method for synthesis of carboxylic acid esters that are used as components of lacquered resins and components of paint-and varnish materials, especially, as plasticizer for plastics. Method involves interaction of di- or polycarboxylic acids or their anhydrides with alcohols wherein reaction water is removed by azeotropic distillation with alcohol, and liquid removed from reaction by azeotropic distillation is replaced with alcohol completely again. The improvement of periodic method used in synthesis of esters provides enhancing yield of the end product and reducing the reaction process time.
EFFECT: improved method of synthesis.
5 cl, 4 ex
Title | Year | Author | Number |
---|---|---|---|
METHOD FOR PRODUCING CARBOXYLIC ACID ESTERS AND THEIR APPLICATION AS PLASTICIZERS | 2014 |
|
RU2636586C1 |
METHOD OF OBTAINING DIESTERS OF TEREPHTHALIC ACID | 2015 |
|
RU2648983C1 |
METHOD FOR PRODUCING DIESTERS OF TEREPHTHALIC ACID WITH BACK ALCOHOL ENRICHMENT | 2015 |
|
RU2665579C1 |
PROCESS FOR PREPARATION OF DIESTERS OF TEREPHTHALIC ACID WITH PUMPING OF THE REACTION MIXTURE | 2015 |
|
RU2668964C1 |
METHOD FOR OBTAINING CARBOXYLIC ACID ESTERS IN PRESENCE OF TITANIUM-CONTAINING CATALYST | 2014 |
|
RU2656338C1 |
METHOD OF PREPARING 2,2,4-TRIMETHYL-3-HYDROXYPENTYL ISOBUTYRATE BASED ESTERS | 1995 |
|
RU2114099C1 |
METHOD OF PRODUCING ESTERS | 0 |
|
SU589740A1 |
PROCESS FOR PRODUCING ESTERS | 0 |
|
SU979328A1 |
METHOD OF PRODUCING ESTERS FROM CAPROLACTAM PRODUCTION WASTES | 2010 |
|
RU2422434C1 |
PROCESS FOR PREPARING ESTERS | 0 |
|
SU1038335A1 |
Authors
Dates
2006-09-10—Published
2001-09-04—Filed