FIELD: organosilicon compounds in rubber industry.
SUBSTANCE: invention provides organosilicon compounds of formula I and/or II:
, where R represents methyl or ethyl group; R', identical or different, branched or linear C9-C30-alkyl or C9-C30-alkenyl, aryl, arylalkyl, branched or linear C2-C30-alkyl ether group, branched or linear C2-C30-alkyl polyether group, R''' 3Si group, wherein R''' represents branched or linear alkyl or alkenyl, arylalkyl, or aryl; R' represents branched or linear, saturated or unsaturated aliphatic, aromatic, or mixed aliphatic/aromatic group with double bond; X is O(C=O)-R''' when n=1 and m=1, SH when n=1 and m=1, S when n=2 and m=1 to 10 and mixture thereof, S(C=O)-R''' when n=1 and m=1, or H when n=1 and m=1; which are prepared by reaction of silanes of general formula III:
with alcohols of general formula R'-OH, which reaction also produces R-OH. The latter is continuously separated from reaction mixture.
EFFECT: extended resource of curing agents in rubber vulcanization processes.
8 cl, 7 tbl, 25 ex
Title | Year | Author | Number |
---|---|---|---|
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|
RU2348642C2 |
RUBBER MIXTURES | 2007 |
|
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|
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RU2762110C2 |
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|
RU2387659C2 |
METHOD FOR SYNTHESIS OF MERCAPTOORGANYL(ALKOXYSILANES) | 2005 |
|
RU2388763C2 |
METHOD OF OBTAINING (MERCAPTOORGANYL)ALKOXYSILANES | 2004 |
|
RU2360917C2 |
Authors
Dates
2006-10-20—Published
2002-08-05—Filed