FIELD: chemistry.
SUBSTANCE: invention relates to methods for synthesis of mercaptoorganyl(alkoxysilanes). Proposed is a method for synthesis of mercaptoorganyl(alkoxysilanes) through hydrogenation bis(alkoxysilyl-organyl)polysulphides in a non-alcohol solvent under the effect of hydrogen and in the presence of a transition metal based catalyst without addition of alcohols, H2S or water. The proposed method can be realised in periodic and in continuous modes and ensures high conversion.
EFFECT: design of a method for synthesis of mercaptoorganyl(alkoxysilanes) through reductive splitting of bis(alkoxysilylorganyl)polysulphides, which avoids additional use of water, alcohols and hydrogen sulphide and ensures high conversion.
13 cl, 5 tbl, 17 ex
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Authors
Dates
2010-05-10—Published
2005-09-06—Filed