[(HETERYLONIO)METHYLCARBONYLOXYPOLY(ALKYLENEOXY)]-[(AMMONIO)METHYLCARBONYLOXYPOLY(ALKYLENEOXY)]PROPANE TRICHLORIDES POSSESSING EMULSIFYING PROPERTIES FOR AQUEOUS-BITUMEN AND AQUEOUS-MAZUT EMULSIONS AND METHOD FOR THEIR PREPARING Russian patent published in 2006 - IPC C07D295/125 C07D295/84 C08G65/332 C08G65/333 B01F17/18 C08L95/00 

FIELD: organic chemistry, chemical technology.

SUBSTANCE: invention relates to novel [(heterylonio)-methylcarbonyloxypoly(alkyleneoxy)]-[(ammonio)methylcarbonyloxypoly(alkyleneoxy)]propane trichlorides of the general formula: wherein: at X⁺ = Y⁺ means X⁺ means -N⁺R¹R²R³ wherein R¹ = R² means hydrogen atom (H); R³ means aliphatic hydrocarbon radical comprising 10-16 carbon atoms; a + c + e (total degree of oxypropylation) = 49; b + d + f (total degree of oxyethylation) = 9; at X⁺ = Y⁺ means Z⁺ means -N⁺R¹R²R³ wherein R¹ = R² means H; R³ means aliphatic hydrocarbon radical comprising 10-16 carbon atoms; a + c + e = 55; b + d + f = 10; at X⁺ means Y⁺ = Z⁺ means -N⁺R¹R²R wherein R¹ = R² means H; R³ means aliphatic hydrocarbon radical comprising 10-16 carbon atoms; a + c + e = 49; b + d + f = 9; at X⁺ means Y⁺ = Z⁺ means -N⁺R¹R²R³ wherein R¹ = R² means H; R³ means aliphatic hydrocarbon radical comprising 10-16 carbon atoms; a + c + e = 55; b + d + f = 10; at X⁺ means Y⁺ = Z⁺ means -N⁺R¹R²R³ wherein R¹ = R² means H; R³ means aliphatic hydrocarbon radical comprising 10-16 carbon atoms; a + c + e = 49; b + d + f = 0; at X⁺ means Y⁺ = Z⁺ means -N⁺R¹R²R³ wherein R¹ = R² means H; R³ means aliphatic hydrocarbon radical comprising 10-16 carbon atoms; a + c + e = 55; b + d + f = 0; at X⁺ = Y⁺ means Z⁺ means -N⁺R¹R²R³ wherein R¹ = R² means H; R³ means aliphatic hydrocarbon radical comprising 10-16 carbon atoms; a + c + e = 49; b + d + f = 0; at X⁺ = Y⁺ means Z⁺ means -N⁺R¹R²R³ wherein R¹ = R² means H; R³ means aliphatic hydrocarbon radical comprising 10-16 carbon atoms; a + c + e = 55; b + d + f = 0, and to a method for their synthesis. Method involves interaction of 1,2,3-tris-[hydroxypoly(alkyleneoxy)]propane of the formula: wherein a + c + e = 55; b + d + f = 0-10 with monochloroacetic acid in the presence of acid catalysts, in organic solvent medium and with azeotropic removal of formed water and the following treatment at heating of the synthesized reaction product^{with a mixture of morpholine and aliphatic amine in the molar ratio of reagents - hydroxyl derivative of propane: monochloroacetic acid : morpholine : aliphatic amine = 1:(3.0-3.2):(1.0-2.1):(1.0-2.1), respectively and wherein the total amount of morpholine and aliphatic amine is 3.0-3.2 mole. Novel compounds possess emulsifying properties for aqueous-bitumen and aqueous-mazut emulsions.}

EFFECT: improved method of synthesis, valuable properties of compounds.

6 cl, 2 tbl, 8 ex