FIELD: organic chemistry.
SUBSTANCE: invention relates to compounds of general formula , wherein: when a+c+e = 49, b+d+f = 9, x = 3; when a+c+e = 55, b+d+f = 10, x = 3; when , a+c+e=49, b+d+f=9 x=3; when , , a+c+e = 55, b+d+f = 10, x = 3; when a+c+e = 49, b+d+f = 9, x = 3; when a+c+e = 55, b+d+f = 10, x = 3; when G=Q=M=-N+H2CH2CH2NH2, a+c+e = 49, b+d+f = 9, x = 3; when G=Q=M=-N+H2CH2CH2NH2, a+c+e = 55, b+d+f = 10, x = 3; when G=Q=-N+H2CH2CH2NH2, M=-Cl, a+c+e = 49, b+d+f = 9, x = 2; when G=Q=-N+H2CH2CH2NH2, M=-Cl, a+c+e = 55, b+d+f = 10, x = 2; when G=Q=M=-N+H2CH2CH2OH, a+c+e = 49, b+d+f = 9, x = 3; when G=Q=M=-N+H2CH2CH2OH, a+c+e = 55, b+d+f = 10, x = 3; when , , a+c+e = 49, b+d+f = 0, x = 3; when , , a+c+e = 55, b+d+f = 0, x = 3. Also disclosed is method for production of abovementioned compounds by interaction of 1,2,3-tris[hydroxypoly(alkyleneoxy)]-propanes with monochloroacetic acid in presence of acetic catalyst in medium of boiling organic solvent with azeotropic removing of formed water followed by treatment at heating of obtained product in polar solvent medium with aliphatic amines of formula R1R2R3N, wherein R1=R2=H; R3= CH2CH2NH2, CH2CH2OH or with heterocyclic amines (pyridines) of formula , wherein R5=H, CH3, or with mixture of morpholine and pyridine in molar ratio of hydroxy propane derivative: monochloroacetic acid:morpholine:pyridine = 1:3.0-3.2:1.0-2.1:1.0:2.1, respectively. Total amount of morpholine and pyridine is 3-3.2 moles.
EFFECT: new compounds with fungicidal activity.
5 cl, 1 tbl, 14 ex
Title | Year | Author | Number |
---|---|---|---|
1,2,3-TRIS-[(AMMONIO)METHYLCARBONYLOXYPOLY(ALKYLENEOXY)]-PROPANE TRICHLORIDES POSSESSING BACTERICIDAL AND FUNGICIDE ACTIVITY AND DEMULSIFYING PROPERTY OF PETROLEUM EMULSION AND METHOD FOR THEIR PREPARING | 2005 |
|
RU2284316C1 |
1,2,3-TRIS-[(AMMONIO)METHYLCARBONYLOXYPOLY(ALKYLENEOXY)]-PROPANE TRICHLORIDES POSSESSING PROPERTY OF EMULGATORS OF AQUEOUS-MAZUT EMULSION AND METHOD FOR THEIR PREPARING | 2005 |
|
RU2284988C1 |
[(HETERYLONIO)METHYLCARBONYLOXYPOLY(ALKYLENEOXY)]-[(AMMONIO)METHYLCARBONYLOXYPOLY(ALKYLENEOXY)]PROPANE TRICHLORIDES POSSESSING EMULSIFYING PROPERTIES FOR AQUEOUS-BITUMEN AND AQUEOUS-MAZUT EMULSIONS AND METHOD FOR THEIR PREPARING | 2005 |
|
RU2286990C1 |
[(AMMONIA)METHYLCARBONYLOXYPOLY(ALKLYLENEOXY)]-PROPANE CHLORIDES HAVING BACTERICIDAL ACTIVITY AND METHOD FOR PRODUCTION THEREOF | 2005 |
|
RU2308467C2 |
1,2,3-TRIS[(AMMONIA)METHYLCARBONYLOXYPOLY(ALKLYLENEOXY)]-PROPANE TRICHLORIDES HAVING BACTERICIDAL AND FUNGICIDAL ACTIVITY AND METHOD FOR PRODUCTION THEREOF | 2005 |
|
RU2308468C2 |
{[1-(AMMONIO)-3,5,7-TRIAZAADAMANTYL]-METHYLCARBONYLOXYPOLY-(ALKYLENEOXY)}PROPANE CHLORIDE POSSESSING BACTERICIDAL AND FUNGICIDE ACTIVITY AND METHOD FOR THEIR PREPARING | 2005 |
|
RU2288920C1 |
1,2,3-TRIS-{[AMINOPOLY(ETHYLENEAMINO)ETHYLAMMONIO]-METHYLCARBONYLOXYPOLY(ALKYLENEOXY)]}PROPANE TRICHLORIDES POSSESSING FUNGICIDE ACTIVITY, PROPERTY OF EMULSIFIER OF CATIONIC BITUMEN EMULSION, CAPACITY TO ENHANCE ADHESION OF BITUMEN TO MINERAL MATERIALS AND METHOD FOR THEIR PREPARING | 2005 |
|
RU2284317C1 |
TRIS-[(AMMONIO)METHYLCARBONYLOXYPOLY-(2-METHYLETHYLENOXY)]PROPANE TRICHLORIDES POSSESSING PROPERTY OF EMULSIFIER OF AQUEOUS-BITUMEN EMULSIONS AND METHOD FOR THEIR PREPARING | 2005 |
|
RU2294337C1 |
METHOD FOR PREPARING ADDITION AGENT AS REGULATORS OF VISCOELASTIC PROPERTY ASSOCIATED MULTICOMPONENT PETROLEUM SYSTEMS | 2005 |
|
RU2285035C1 |
PENTA-{[POLY-(ETHYLENEOXY)CARBONYLMETHYL]-HETERYLONIUM}-DERIVATIVES OF TRIPHENOLS AND METHOD FOR THEIR PREPARING, METHOD FOR HYDROPHILIZATION OF EPOXY POLYMERS, METALLIC ARTICLE FETTLED BY THIS POLYMER AND METHOD FOR PREVENTION OF PRECIPITATION OF ASPHALT-RESINOUS-PARAFFIN DEPOSITS FROM PETROLEUM | 2006 |
|
RU2318800C1 |
Authors
Dates
2007-10-20—Published
2005-07-06—Filed