FIELD: desulfurization and hydrogenation catalysts.
SUBSTANCE: invention relates to preparing hydrodesulfurization and dearomatization catalysts useful in processes of deep purification of motor fuels from sulfur-containing compounds and aromatics. A sulfur-resistant catalyst is provided including active component deposited on porous inorganic support including montmorillonite or alumina and characterized by that support is composed of zeolite H-ZSM-5 with Si/Al atomic ratio 17-45 (80-65%) and montmorillonite or alumina (20-35%), while active component is platinum or palladium, platinum and palladium in quantities, respectively, 0.2-2.0, 0.2-1,5. and 0.4-0.2% based on the total weight of catalyst. Described is also catalyst comprising platinum (0.2-2.0%) or palladium (0.2-1.5%), or platinum and palladium (0.4-2.0%) supported by Ca or Na form of montmorillonite, and also catalyst with the same active components supported by zeolite H-ZSM-5 with Si/Al atomic ratio 17-45.
EFFECT: increased sulfur-caused deactivation resistance of catalyst at moderate temperatures and under conditions efficiency in hydrodesulfurization and aromatics hydrogenation processes.
8 cl, 4 tbl, 30 ex
Title | Year | Author | Number |
---|---|---|---|
CATALYST, CARRIER PREPARATION METHOD, CATALYST PREPARATION METHOD, AND DIESEL FRACTION HYDRODESULFURIZATION PROCESS | 2006 |
|
RU2311959C1 |
CATALYST, METHOD FOR PREPARATION THEREOF, METHOD FOR PREPARING CARRIER FOR THIS CATALYST, AND DIESEL FRACTION DESULFURIZATION PROCESS | 2006 |
|
RU2313389C1 |
CATALYST, PREPARATION METHOD THEREOF AND NONOXIDATIVE METHANE CONVERSION PROCESS | 2010 |
|
RU2438779C1 |
METHOD TO PREPARE CATALYST FOR DETOXICATION OF EXHAUST GASES (VERSIONS) | 2008 |
|
RU2388532C1 |
METHOD FOR PRODUCING LOW-FOLDING DIESEL FUEL | 2022 |
|
RU2785685C1 |
CATALYST, METHOD OF ITS PREPARATION (VERSIONS) AND PROCESS OF HYDRODESULPHURISATION OF DIESEL FRACTIONS | 2007 |
|
RU2342994C1 |
CATALYST, METHOD OF MANUFACTURING THEREOF AND PROCESS OF DIESEL FUEL HYDROISOMERISATION | 2013 |
|
RU2536585C1 |
METHOD OF PREPARING MONO- AND BIMETALLIC CATALYST AND PROCESSES INVOLVING OXYGEN AND/OR HYDROGEN | 2006 |
|
RU2316394C1 |
CATALYST FOR THE SECOND STAGE OF HYDROCRACKING | 2021 |
|
RU2779444C1 |
CATALYST AND METHOD OF PRODUCING SYNTHETIC GAS | 2010 |
|
RU2453366C1 |
Authors
Dates
2007-04-10—Published
2005-08-22—Filed