FIELD: chemistry.
SUBSTANCE: described is catalyst of hydroisomerisation, including zeolite of ZSM-23 type, palladium and aluminium oxide, containing components in the following concentrations, wt %: zeolite of ZSM-23- 50-80, palladium - not more than 0.6; boron 1.0-3.0; Al2O3 - the remaining part, which has pore volume not less than 0.25 cm3/g, specific surface not less than 150 m2/g, average diameter of pores not smaller than 4 nm. Method of catalyst preparation consists in soaking zeolite ZSM-23-containing carrier with boric acid solution with the following drying and calcinations, and further soaking with water solution of palladium nitrate with the following drying and calcinations. Described is process of hydroisomerisation of Diesel fuel, which contains not more than 30 ppm of sulphur, carried out at 320-340°C, pressure 2.5-6.5 MPa, volume rate of raw material supply 2-6 h-1, volume ratio hydrogen/raw material - 200-600 nm3/m3 in presence of catalyst with given above composition.
EFFECT: obtaining catalyst, which makes it possible to carry out process of hydroisomerisation with obtaining Diesel fuels with lower pour point, with high output and cetane number.
12 cl, 2 tbl, 4 ex
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Authors
Dates
2014-12-27—Published
2013-09-27—Filed