FIELD: polymerization catalysts.
SUBSTANCE: invention provides rare-earth element carboxylate composition used as a part of catalytic system for polymerization of conjugated dienes and containing rare-earth element carboxylate and organic solvent, which composition is characterized by additionally containing oxyalkylenated C1-C20-alcohol with molecular mass 90 to 100000 or mixture of such oxyalkylenated alcohols. Described is also preparation of liquid rare-earth element carboxylate composition as well as conjugated diene polymerization process in presence of catalytic system to give polymer with high content of 1,4-cis units.
EFFECT: enabled preparation of stable composition suitable for preparation of stereospecific diene polymerization catalyst.
5 cl, 23 ex
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Authors
Dates
2007-04-20—Published
2006-03-09—Filed