FIELD: chemistry.
SUBSTANCE: invention relates to a technique of producing cis-1,4-polydienes by polymerising butadiene, isoprene or mixtures thereof in a medium of a hydrocarbon solvent in the presence of a rare-earth element based Ziegler-Natta catalyst. In the final stage of the polymerisation process, an α-olefin and maleic anhydride copolymer is added to the reaction mass in ratio of cis-1,4-polydiene to copolymer of 1:1·10-4 - 1·10-1.
EFFECT: improved properties of cis-1,4-polydienes, cold flow, dynamic viscosity and polydispersity.
2 tbl, 7 ex
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Authors
Dates
2013-12-10—Published
2012-05-22—Filed