FIELD: chemistry.
SUBSTANCE: invention relates to the industry of synthetic rubber used in production of tires, rubber articles, in electrical engineering and other fields. Described is a method of producing modified polydienes in an organic solvent medium, on a catalyst system comprising a lanthanide, an organoaluminium compound and a halogen-containing component, with subsequent end modification of the obtained "pseudo-living" polymer with at least one compound selected from a group of heterocyclic nitrogen-containing compounds. Present invention also relates to modified polydienes obtained using this method. Invention also relates to rubber mixtures based on obtained polydienes.
EFFECT: obtained modified polydiene is characterized by high degree of modification (not less than 90 %), high content of 1,4-cis-links and narrow molecular weight distribution, improved processability at the stage of rubber mixing.
21 cl, 2 tbl, 20 ex
Title | Year | Author | Number |
---|---|---|---|
METHOD FOR OBTAINING MODIFIED POLYDIENES | 2020 |
|
RU2804706C1 |
METHOD OF PRODUCING A COMPOSITION FOR MODIFYING 1,4-CIS-POLYDIENE, A METHOD OF PRODUCING MODIFIED 1,4-CIS-POLYDIENE | 2018 |
|
RU2688164C1 |
MODIFIED POLYDIENES AND METHOD FOR THEIR PRODUCTION | 2019 |
|
RU2803602C1 |
METHOD FOR PREPARING A SYSTEM FOR MODIFICATION OF POLYDIENES, MODIFIED POLYDIENES, RUBBER MIXTURES BASED ON MODIFIED POLYDIENES | 2017 |
|
RU2675540C1 |
METHOD FOR PRODUCING MODIFIED POLYDIENES (EMBODIMENTS) | 2020 |
|
RU2802970C1 |
METHOD OF PROCUCING MODIFIED CIS-1,4(CO) | 2010 |
|
RU2426747C1 |
METHOD FOR PRODUCING BRANCHED POLYDIENE | 2019 |
|
RU2815816C1 |
BRANCHED POLYDIENES AND RUBBER MIXTURES BASED ON THEM | 2019 |
|
RU2809256C1 |
METHOD FOR PRODUCING 1,4-CIS-POLYBUTADIENE | 2015 |
|
RU2626967C2 |
METHOD OF PRODUCING DIENE COPOLYMERS | 2018 |
|
RU2701930C1 |
Authors
Dates
2020-07-23—Published
2016-11-10—Filed