CATALYST AND OIL STOCK HYDROTREATMENT PROCESS UTILIZING IT Russian patent published in 2007 - IPC B01J23/85 B01J27/12 C10G47/08 C10G45/08 

Abstract RU 2301703 C1

FIELD: petroleum processing.

SUBSTANCE: invention provides oil stock hydrotreatment catalyst containing alumina-supported hydrogenation components: cobalt, molybdenum, and tungsten in the form of oxides at weight ratio Co/Mo/W = 20:45:35 (15-25% in total), aluminum fluoride (10-30%), and promoter (2.5-16.5%): silicon oxide and/or rare-earth element oxides, in particular lanthanum oxide or lanthanum/cerium oxide mixture. Promoter may further contain up to 3% zirconium oxide. Alumina functions as binding material. Invention also covers oil stock hydrotreatment process, which is conducted in presence of claimed catalyst at 340-430°C, pressure 3-10 MPa, oil stock flow rate 0.5 to 3 h-1, and hydrogen-to-oil stock ratio 250 to 1000 nm3/m3. Catalyst is characterized by elevated hydrocracking and hydro-desulfurization activity and selectivity in oil stock hydrotreatment processes resulting in production of diesel distillates meeting European requirements (EN-590). Catalyst can be prepared on any existing catalyst preparation equipment.

EFFECT: simplified catalyst preparation technology and avoided formation of effluents.

5 cl, 3 tbl, 6 ex

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RU 2 301 703 C1

Authors

Konoval'Chikov Oleg Dmitrievich

Khavkin Vsevolod Arturovich

Guljaeva Ljudmila Alekseevna

Reznichenko Irina Dmitrievna

Bocharov Aleksandr Petrovich

Krasil'Nikova Ljudmila Aleksandrovna

Mis'Ko Ol'Ga Mikhajlovna

Loshchenkova Irina Nikolaevna

Bychkova Dina Moiseevna

Dates

2007-06-27Published

2006-03-15Filed