FIELD: polymerization catalysts.
SUBSTANCE: invention relates to an area of supported olefin polymerization organometallic catalysts containing organometallic complex LMX2, wherein L represents bic(imido)pyridine, M period IV transition metal (Ti, V, Cr. Fe. Co), X halogen, alkoxy or alkyl group, deposited on oxide support, namely large-pore silica gel with pore volume no greater than 1.3 cm3/g and specific surface not exciding 250 m2/g, which, prior to deposition of complex LMX2, is treated with trialkylaluminum AlR3 (R = Et or i-Bu) followed by heating SiO2/AlR3 product and dehydroxylation of support obtained.
EFFECT: simplified and reduced in price method while preserving high catalyst activity and yield of polymer.
4 cl, 1 tbl, 11 ex
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Authors
Dates
2007-07-10—Published
2006-05-26—Filed