FIELD: hydrogenation-dehydrogenation catalysts.
SUBSTANCE: invention is dealing with development of effective catalyst for hydrogenation of unsaturated hydrocarbons (alkenes, alkynes) and a method for preparation thereof, which could be used in fine organic synthesis. Catalyst contains palladium compound and a modifying additive, the former being palladium bis-acetylacetonate and the latter phosphine (PH3) at molar ratio ranging from 1:0.1 to 1:1, respectively. Preparation of catalyst is based on reduction of palladium compound with hydrogen in presence of phosphine, which is introduced before reduction of palladium bis-acetylacetonate at catalytic system formation temperature: 70-80°C. Optimal time for molding of catalyst is 10-15 min.
EFFECT: increased catalytic activity when carrying out catalytic process under mild conditions (at room temperature and atmospheric pressure) and reduced catalyst preparation expenses.
2 cl, 5 tbl, 24 ex
Title | Year | Author | Number |
---|---|---|---|
PALLADIUM HYDROGENATION CATALYST AND METHOD TO MANUFACTURE THEREOF | 2006 |
|
RU2323776C2 |
METHOD FOR PRODUCING PALLADIUM-CONTAINING CATALYST FOR HYDROGENATION OF ACETYLENE COMPOUNDS | 2022 |
|
RU2814116C1 |
NICKEL HYDROGENATION CATALYST AND PREPARATION METHOD THEREOF | 2009 |
|
RU2411228C1 |
METHOD OF PRODUCING O-CHLOROANILINE (VERSIONS) | 2014 |
|
RU2556222C1 |
HYDROGENATION NICKEL CATALYST | 2014 |
|
RU2565673C1 |
METHOD OF PRODUCING O-CHLOROANILINE | 2015 |
|
RU2606394C1 |
METHOD FOR PREPARATION OF BUTENE-2-DIOL-1,4 | 2021 |
|
RU2788753C1 |
COMPLEX NICKEL HYDROGENATION CATALYST | 2022 |
|
RU2790674C1 |
METHOD OF HYDROGENATING ACETYLENIC ALCOHOLS (VERSIONS) | 2020 |
|
RU2734459C1 |
METHOD OF PRODUCING HYDROGEN PEROXIDE | 2018 |
|
RU2687449C1 |
Authors
Dates
2007-08-20—Published
2005-12-28—Filed